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Electrochemical SPM study of 2D phase and 3D phase formation of Zn at the ionic liquid / Au(111) interface [online]

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ISBN: 3937300090 Year: DOI: 10.5445/KSP/1132004 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Chemistry (General)
Added to DOAB on : 2019-07-30 20:01:58

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Zn electrodeposition in the under- (UPD) and overpotential (OPD) ranges by means of in-situ Scanning Tunneling Microscopy (STM) was examined, supported by in-situ cyclic voltammetry and chronoamperometrie. The underpotential deposition of Zn follows a layer-by-layer growth. For the first time the formation of three successive Zn monolayers has been observed in the UPD range. It has been shown, that the UPD of Zn is complicated due to surface alloying. The same growth mechanism extends from the UPD into OPD range until Al bulk deposition sets in. The UPD of Al at 100 mV vs. Zn/Zn(II) is marked by Moiré pattern formation. For the first time in this system the effective tunneling barrier f has been measured by STS. A first insight into the 2D phase formation of electrodeposited Zn at the electrolyte / electrode interface was obtained from STM images at various times and potentials. Before a coherent layer is formed wormlike structures are observed characteristic of spinodal decomposition. This implies a first order phase transition, which has been resolved here for the first time for 2D electrodeposition.

Advancements in Gel Science—A Special Issue in Memory of Toyoichi Tanaka

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ISBN: 9783039213436 9783039213443 Year: Pages: 178 DOI: 10.3390/books978-3-03921-344-3 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Chemical Technology
Added to DOAB on : 2019-12-09 11:49:15
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A gel is a state of matter that consists of a three-dimensional cross-linked polymer network and a large amount of solvent. Because of their structural characteristics, gels play important roles in science and technology. The science of gels has attracted much attention since the discovery of the volume phase transition by Professor Toyoichi Tanala at MIT in 1978. MDPI planned to publish a Special Issue in Gels to celebrate the 40th anniversary of this discovery, which received submissions of 13 original papers and one review from various areas of science. We believe that readers will find this Special Issue informative as to the recent advancements of gel research and the broad background of gel science.

Keywords

gel --- thermoresponsive property --- monomer sequence --- co-crosslinking --- copolymerization --- acrylamide derivative --- swelling --- volume phase transition --- agarose gel --- compression --- solvent transport --- sucrose --- xylitol --- volume phase transition --- effects of electric charge --- swelling of thermosensitive gels --- sol-gel transition --- site-bond correlated-percolation model for polymer gelation --- gelation temperature --- cloud point temperature --- spinodal temperature --- spinodal decomposition --- janus particle --- anisotropic shape --- phase separation --- wetting --- micrometric confinement --- micropipette aspiration --- PVA gel --- gamma ray sterilization --- artificial hydrogel cartilage --- frictional property --- wear --- xerogel --- Brunauer-Emmett-Teller theory --- Barrett-Joyner-Halenda analysis --- temperature --- solids content --- drying --- solvent exchange --- microgel --- electrophoresis --- light scattering --- paint coating --- wrinkle --- swelling --- buckling --- Sephadex® (crosslinked dextran) --- crosslink density (density of crosslinks) --- ice grain --- ice crystallization during rewarming --- glassy water --- X-ray CT --- XRD --- poly(vinyl alcohol) --- chemical gel --- microcrystallite --- hydrogen bond --- swelling behavior --- hysteresis --- hydrogel --- friction --- fatigue --- wear --- fracture --- crack --- adhesion --- delamination --- poly (acryl amide) gel --- time domain reflectometry (TDR) of dielectric spectroscopy --- pulse field gradient spin echo method of nuclear magnetic resonance (PFG-NMR) --- scaling analysis --- fractal analysis --- heterogeneous gelation dynamics --- moving boundary picture --- phase transition dynamics --- kinetic coefficient --- blood coagulation --- n/a

Failure Mechanisms in Alloys

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ISBN: 9783039282760 9783039282777 Year: Pages: 476 DOI: 10.3390/books978-3-03928-277-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-04-07 23:07:09
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The era of lean production and excellence in manufacturing, advancing with sustainable development, demands the rational utilization of raw materials and energy resources, adopting cleaner and environmentally-friendly industrial processes. In view of the new industrial revolution, through digital transformation, the exploitation of smart and sophisticated materials systems, the need of minimizing scrap and increasing efficiency, reliability and lifetime and, on the other hand, the pursuit of fuel economy and limitation of carbon footprint, are necessary conditions for the imminent growth in a highly competitive economy. Failure analysis is an interdisciplinary scientific topic, reflecting the opinions and interpretations coming from a systematic evidence-gathering procedure, embracing various important sectors, imparting knowledge, and substantiating improvement practices. The deep understanding of material/component role (e.g., rotating shaft, extrusion die, gas pipeline) and properties will be of central importance for fitness for purpose in certain industrial processes and applications. Finally, it is hoped and strongly believed that the accumulation of additional knowledge in the field of failure mechanisms and the adoption of the principles, philosophy, and deep understanding of failure analysis process approach will strongly promote the learning concept, as a continuously evolving process leading to personal and social progress and prosperity.

Keywords

impingement --- erosion corrosion --- API 5L-X65 --- flow loop --- wear scar --- creep fatigue --- crack growth --- grain boundary --- hydrogen-assisted cracking --- corrosion --- SOHIC --- cleavage fracture --- cold-working process --- surface-cracking process --- impact toughness --- strength --- low temperatures --- austenitic stainless steels --- pipeline steel --- tensile stress --- corrosion --- potentiodynamic polarization --- EIS --- brass extrusion --- CFD simulation --- extrusion failures --- plastic deformation processing --- finite element analysis --- inverse modeling --- post-necking hardening --- biaxial tensile test --- elevated temperature --- reliability design --- helix upper dispenser --- fracture --- parametric accelerated life testing --- faulty designs --- metal components --- fracture mechanisms --- fractography --- fracture mechanics --- quality improvement --- finite element modeling --- nanocrystalline materials --- elastic moduli --- yield strength --- cast duplex stainless steels --- thermal aging --- tensile deformation --- spinodal decomposition --- smooth particle hydrodynamics --- Titanium alloy machining --- numerical simulation --- cutting forces --- chip formation --- fracture --- iterative FEM Method --- GISSMO Model --- softening --- macroscopic strength criterion --- isotropic metals --- fracture plane --- linear Mohr–Coulomb criterion --- failure mechanism --- W-30Cu --- microstructure homogeneity --- dynamic compression strength --- ductility --- failure mechanism --- slow-rate machining --- chip formation --- shape --- temperature --- microhardness HV --- creep --- steam reforming --- carbides --- G-phase --- aging --- cast reformer tubes --- hot stamping --- press hardening --- austenitizing furnace --- high temperature fatigue --- thermal distortion --- conveying system --- refractory steels --- furnace component failure --- ductile irons --- tensile tests --- mechanical properties --- constitutive equations --- quality assessment --- shear angle --- chip root --- shape --- built-up edge --- slow-rate machining --- convection tubes --- AISI 304 stainless steel --- failure analysis --- sensitization --- bake hardening --- dent resistance --- failure study --- polynomial regression --- yield strength --- automotive steels --- reformer tubes --- HP-Mod --- failure analysis --- creep --- surface modification techniques --- degradation of protective layers --- lubrication --- nitrocarburizing --- hardfacings --- thermal-sprayed coatings --- finite element analysis --- forward slip prediction --- strip marking method --- multilinear regression --- micro flexible rolling --- thickness transition area --- 3D Voronoi modelling --- automotive --- 6063 Alloy --- EBSD --- bendability --- fractography --- modeling --- texture --- tribological properties --- wear --- surface treatment --- self-equalizing bearing --- n/a

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