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Processing-Structure-Properties Relationships in Polymers

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ISBN: 9783039218806 9783039218813 Year: Pages: 400 DOI: 10.3390/books978-3-03921-881-3 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-01-07 09:08:26
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This collection of research and review papers is aimed at depicting the state of the art on the possible correlations between processing variables, obtained structure and special properties which this structure induces on the plastic part. The extraordinary capacity of plastics to modify their properties according to a particular structure is evidenced for several transformation processes and for many applications. The final common goal is to take profit of this peculiar capacity of plastics by inducing, through a suitable processing, a specific spatial organization.

Keywords

carbon nanotube --- homogeneous dispersion --- ethylene vinyl acetate --- mechanical performance --- electrical conductivity --- microencapsulation --- melamine polyphosphate --- polyurethane --- composite --- flame retardant --- biodegradable nanofibers --- PLGA --- collagen --- epinephrine --- lidocaine --- polyimide film --- linear coefficient of thermal expansion (CTE) --- copper clad laminate --- structure and properties --- polymorphism --- isotactic polypropylene --- deformation --- phase transitions --- uniaxial compression --- uniaxial tensile deformation --- temperature --- in situ X-ray --- cavitation --- indentation --- Harmonix AFM --- polymer morphology --- mechanical properties --- ultra-high molecular weight polyethylene (UHMWPE) --- microcellular injection molding --- supercritical fluid --- supercritical N2 --- supercritical CO2 --- tissue engineering and regenerative medicine --- bioresorbable polymers --- 3D printing/additive manufacturing --- fused filament fabrication/fused deposition modelling --- degradation --- physicochemical characterization --- polycaprolactone --- layered double hydroxides --- ionic liquids --- PLA --- reactive blending --- biobased films --- graphene --- nanoreinforcement --- curing rate --- epoxy microstructure --- fatigue --- composites --- critical gel --- poly(lactic acid) --- carbon black --- graphite --- polymer blend --- poly(ethylene terephthalate) --- intrinsic viscosity --- polyolefin --- compatibilizer --- isotactic polypropylene --- stress-induced phase transitions --- structural analysis --- X-ray diffraction --- polyoxymethylene (POM) --- octakis[(3-glycidoxypropyl)dimethylsiloxy]octasilsesquioxane (GPOSS) --- composites --- morphology --- mechanical properties --- conductive filler --- orientation --- conductive polymer composites --- foam --- model --- PLLA --- bioresorbable vascular scaffolds --- stretch blow molding --- biaxial elongation --- SAXS --- WAXS --- microfibrillar composites --- crystalline morphology --- crystallinity --- mechanical properties --- crystallisation --- morphology --- nanoparticles --- shear --- flow --- orientation --- poly(?-caprolactone) --- polyvinyl butyral --- hydrophobicity --- contact angle --- polypropylene --- atomic force microscopy --- injection molding --- mold temperature evolution --- polycaprolactone --- ultra-high molecular weight polyethylene --- incremental forming --- SPIF --- XRD --- chain orientation --- temperature sensitive --- gel --- controllable gas permeability --- breathable film --- polymer composite --- processing --- polyamide 6 --- compression molding --- polymorphism --- polyamide 6 --- injection molding --- polymorphism --- humidity --- mechanical properties

Recent Development of Electrospinning for Drug Delivery

Authors: --- ---
ISBN: 9783039281404 9783039281411 Year: Pages: 206 DOI: 10.3390/books978-3-03928-141-1 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Medicine (General) --- Therapeutics
Added to DOAB on : 2020-04-07 23:07:09
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Abstract

Several promising techniques have been developed to overcome the poor solubility and/or membrane permeability properties of new drug candidates, including different fiber formation methods. Electrospinning is one of the most commonly used spinning techniques for fiber formation, induced by the high voltage applied to the drug-loaded solution. With modifying the characteristics of the solution and the spinning parameters, the functionality-related properties of the formulated fibers can be finely tuned. The fiber properties (i.e., high specific surface area, porosity, and the possibility of controlling the crystalline–amorphous phase transitions of the loaded drugs) enable the improved rate and extent of solubility, causing a rapid onset of absorption. However, the enhanced molecular mobility of the amorphous drugs embedded into the fibers is also responsible for their physical–chemical instability. This Special Issue will address new developments in the area of electrospun nanofibers for drug delivery and wound healing applications, covering recent advantages and future directions in electrospun fiber formulations and scalability. Moreover, it serves to highlight and capture the contemporary progress in electrospinning techniques, with particular attention to the industrial feasibility of developing pharmaceutical dosage forms. All aspects of small molecule or biologics-loaded fibrous dosage forms, focusing on the processability, structures and functions, and stability issues, are included.

Keywords

electrospinning --- gentamicin sulfate --- polylactide-co-polycaprolactone --- drug release kinetics --- tissue engineering --- growth factor --- diabetic --- wound healing --- nanocomposite --- electrospinning --- coaxial spinning --- core-sheath nanofibers --- biomedical --- drug delivery --- electrospinning --- scale-up --- processability --- biopharmaceuticals --- oral dosage form --- grinding --- aceclofenac --- nanofiber --- electrospinning --- scanning electron microscopy --- fourier transform infrared spectroscopy --- differential scanning calorimetry --- nanotechnology --- biotechnology --- probiotics --- Lactobacillus --- Lactococcus --- electrospinning --- nanofibers --- drying --- local delivery --- viability --- antibacterial activity --- bacterial bioreporters --- drug release --- electrospinning --- microfibers --- nanofibers --- UV imaging --- wetting --- in situ drug release --- nanofibers --- electrospinning --- poorly water-soluble drug --- piroxicam --- hydroxypropyl methyl cellulose --- polydextrose --- scanning white light interferometry --- nanotechnology --- nanofibers --- traditional electrospinning --- ultrasound-enhanced electrospinning --- drug delivery system --- haemanthamine --- plant-origin alkaloid --- electrospinning --- amphiphilic nanofibers --- self-assembled liposomes --- physical solid-state properties --- drug release --- electrospinning --- PCL --- gelatin --- clove essential oil --- antibacterial --- biocompatibility --- artificial red blood cells --- electrospinning and electrospray --- pectin --- oligochitosan --- hydrogel --- microcapsules --- electrospinning --- wound dressings --- solvent casting --- 3D printing --- polymeric carrier --- n/a

Smart and Functional Polymers

Authors: --- ---
ISBN: 9783039215904 9783039215911 Year: Pages: 306 DOI: 10.3390/books978-3-03921-591-1 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-12-09 11:49:16
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This book is based on the Special Issue of the journal Molecules on “Smart and Functional Polymers”. The collected research and review articles focus on the synthesis and characterization of advanced functional polymers, polymers with specific structures and performances, current improvements in advanced polymer-based materials for various applications, and the opportunities and challenges in the future. The topics cover the emerging synthesis and characterization technology of smart polymers, core?shell structure polymers, stimuli-responsive polymers, anhydrous electrorheological materials fabricated from conducting polymers, reversible polymerization systems, and biomedical polymers for drug delivery and disease theranostics. In summary, this book provides a comprehensive overview of the latest synthesis approaches, representative structures and performances, and various applications of smart and functional polymers. It will serve as a useful reference for all researchers and readers interested in polymer sciences and technologies.

Keywords

amphiphilicity --- phase change --- polyamino acids --- degradability --- fine-tuning --- pH responsive --- poly(methacrylamide)s --- phase transition --- catalyst --- CO2 --- heterogeneous catalysis --- molecular sieve --- polyether imidazole ionic liquid --- Vitamin E --- albumin --- core-shell nanoparticles --- paclitaxel --- multi-drug resistance --- breast cancer --- conducting polymer --- composite --- electrorheological --- smart fluid --- viscoelastic --- controlled polymerization --- reversible polymerization --- sustainable polymers --- pH responsive polymers --- nanomedicine --- tumor imaging --- drug delivery --- polymerization dispersion method --- polyaniline --- polyvinyl alcohol --- glutaraldehyde --- chemical activation --- Glycopolymer --- post-polymerization functionalization --- perfluoroaryl azides --- Staudinger reaction --- castor oil --- biomedical devices --- polyurethanes --- polycaprolactone-diol --- chitosan --- fluoropolymers --- melt-shear organization --- chemical resistance --- solvent responsiveness --- hydrophobicity --- core/shell particles --- emulsion polymerization --- particle processing --- ?-NaYF4 --- rare earth upconversion nanoparticles --- core–shell structure --- hydrogels --- applications --- targeted drug delivery --- drug release --- hydrophobic drug delivery --- clinical translation --- versatile platform --- administration routes --- diverse therapeutic areas --- hearing loss --- saffron --- endophytic exopolysaccharide --- gentamicin --- cochlear hair cell --- polymeric nanoparticles --- stimuli-sensitive polymers --- co-delivery systems --- synergistic effect --- nucleic acid delivery --- chemotherapy --- phenylboronic acid --- gel --- glucose sensitivity --- drug delivery --- diabetes therapy --- amphiphilic copolymer --- hydrolyzable polyurea --- micelle --- controlled drug delivery --- cancer chemotherapy --- polymerization or post-polymerization modification methods --- polymer-based supramolecular chemistry --- stimuli-responsive polymers --- shape memory polymers --- self-healing polymers --- polymers for industrial catalysis --- polymers for water or effluent treatment --- polymers for sensing, separation, and purification --- polymers for fabrication --- renewable polymer materials used for agriculture --- functional polymers used in food science --- polymers for information storage, electronics, and energy conversion --- functional polymers for diagnosis, imaging, drug delivery, and tissue engineering --- polymers with biological activity (e.g., antitumor, antidiabetic, and antimicrobial activity) --- polymer-based medical devices

Bio-Based Polymers for Engineered Green Materials

Authors: ---
ISBN: 9783039289257 / 9783039289264 Year: Pages: 568 DOI: 10.3390/books978-3-03928-926-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-06-09 16:38:57
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With daily signals, Nature is communicating us that its unconscious wicked exploitation is no more sustainable. Our socio-economic system focuses on production increasing without considering the consequences. We are intoxicating ourselves on a daily bases just to allow the system to perpetuate itself. The time to switch into more natural solutions is come and the scientific community is ready to offer more natural product with comparable performance then the market products we are used to deal with. This book collects a broad set of scientific examples in which research groups from all over the world, aim to replace fossil fuel-based solutions with biomass derived materials. In here, some of the most innovative developments in the field of bio-materials are reported considering topics which goes from biomass valorization to the synthesis of high preforming bio-based materials.

Keywords

thermoplastic starch --- corn starch --- chitosan --- crosslinked microparticles --- lignin-containing cellulose nanofibrils --- poly(lactic acid) and composite films --- lignin content --- compatibility --- adsorption --- phenanthrene --- pyrene --- benzoyl cellulose --- stearoyl cellulose --- silkworm cocoons --- dense structure --- porosity --- robust fiber network --- mechanical properties --- photodegradation --- liquid natural rubber --- UV light --- TiO2 anatase --- latex state --- wood modification --- alkali lignin --- water resistance --- dimensional stability --- heat treatment --- polymeric composites --- antifouling --- metal binding --- iron chelation --- polydopamine coating --- free-radical polymerization --- galactoglucomannan --- lignin --- lignin-carbohydrate complex --- ultrafiltration --- precipitation --- hydrogel --- recycling --- thermal degradation --- mechanical degradation --- polylactic acid --- Bioflex --- Solanyl --- PHBV --- poly(lactic acid) --- pulp fibers --- biocomposite --- emulsion-solvent evaporation method --- films --- mechanical properties --- PHA --- mixed microbial cultures --- bioplastics --- feast-famine --- cost --- Peptone --- Microbial nutrient --- Anti-bacterial silver nanoparticle --- Escherichia coli --- Staphylococcus aureus --- tannin --- hemicellulose --- waste biomass --- HSQC-NMR --- pyrolysis mechanism --- hydrotropic treatment --- metal chloride --- delignification --- enzymatic saccharification --- lignocellulosic nanofibrils --- microencapsulated phase change material (MPCM) --- polylactic acid (PLA) --- toughening --- endothermic effect --- kenaf fiber --- hybrid composites --- bio-based --- film --- mechanical properties --- polysaccharides --- resource recovery --- solution casting --- orange waste --- nanocelluloses --- cellulose nanofibers --- cellulose nanocrystals --- bacterial cellulose --- cement --- fiber-cement --- Hatscheck process --- bio-inspired interfaces --- mechanical properties --- thermal stability --- sensitivity --- electrospinning --- tissue engineering --- paper-based scaffolds --- osteoblast proliferation --- polycaprolactone --- biopolymers --- nanoclays --- nanobiocomposites --- extrusion-compounding --- polyhydroxyalkanoates --- thermal properties --- mechanical properties --- differential scanning calorimetry --- nuclear magnetic resonance --- X-ray diffraction --- transparent wood --- chemical composition --- H2O2 bleaching treatment --- physicochemical properties --- cellulose --- electrical resistance --- copper coating --- electroless deposition --- humidity sensor --- strain sensor --- lyocell fiber --- asphalt rubber --- bio-asphalt --- mixing sequence --- workability --- storage stability --- tung oil --- unsaturated polyester resins --- thermosetting polymers --- structure–property relationship --- structural plastics --- ONP fibers --- silanization --- composites --- mechanical properties --- Artemisia vulgaris --- microcellulose fiber --- nanocellulose fibers --- natural fibers --- Bio-based foams --- wastewater treatments --- cationic dyes --- anionic surfactants --- pollutant adsorbents --- tannin polymer --- tannin-furanic foam --- biopolymers --- nanoclays --- bio-nanocomposites --- extrusion-compounding --- polyhydroxyalkanoates --- thermal properties --- microstructure --- volatiles --- autoxidation --- thermal gravimetric analysis --- scanning electron microscope --- headspace solid phase microextraction --- alginate sponge --- two-step lyophilization --- methylene blue --- adsorption capacity --- biomass resources --- hybrid nonisocyanate polyurethane --- solvent- and catalyst-free --- dimer acid --- melt condensation --- bacterial cellulose --- surface modification --- TEMPO oxidation --- one-pot synthesis --- immobilized TEMPO --- physical property --- skincare --- cellulose --- graphene oxide --- ionic liquid --- membrane --- transport properties --- heavy metals --- porous structure --- SAXS --- WAXS --- cellulose --- wood --- lignocellulose --- ionic liquid --- imidazolium --- fractionation --- dissolution --- GC-MS --- kaempferol --- knotwood --- larixol --- taxifolin --- vibrational spectroscopy --- n/a

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english (3)

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