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Catalytic soot oxidation by platinum on sintered metal filters. Influence of the platinum quantity, particle size and location, and investigation of the platinum-soot contact

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ISBN: 9783866441033 Year: Pages: VII, 135 p. DOI: 10.5445/KSP/1000005906 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Chemical Engineering
Added to DOAB on : 2019-07-30 20:02:00
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The great challenge for next years concerning the emission of diesel engines is to develop diesel particle filters (DPF) with catalytic regeneration systems. This work is focused on the global understanding of the diesel soot oxidation on sintered metal filters (SMF). Platinum is studied as reference catalyst. The first objective is to determine which of platinum quantity, platinum particle size, or platinum location exhibits the preponderant influence on the catalytic.

A Commemorative Issue in Honor of Professor Nick Hadjiliadis: Metal Complex Interactions with Nucleic Acids and/or DNA

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ISBN: 9783038975113 9783038975120 Year: Pages: 256 DOI: 10.3390/books978-3-03897-512-0 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Biochemistry --- Biology --- Medicine (General) --- Therapeutics
Added to DOAB on : 2019-02-05 12:36:28
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This Special Issue of the International Journal of Molecular Science comprises a comprehensive study on “Metal Complex Interactions with Nucleic Acids and/or DNA”. This Special Issue has been inspired by the important contribution of Prof. Nick Hadjiliadis to the field of palladium or/and platinum/nucleic acid interactions. It covers a selection of recent research and review articles in the field of metal complex interactions with nucleic acids and/or DNA. Moreover, this Special Issue on "Metal Complexes Interactions with Nucleic Acids and/or DNA" provides an overview of this increasingly diverse field, presenting recent developments and the latest research with particular emphasis on metal-based drugs and metal ion toxicity.

New Results and Advances in PGE Mineralogy in Ni-Cu-Cr-PGE Ore Systems

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ISBN: 9783039217168 9783039217175 Year: Pages: 228 DOI: 10.3390/books978-3-03921-717-5 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-12-09 16:39:37
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The book (Special Issue) presents impressive new results related to a wide spectrum of occurrences of platinum-group minerals (PGM) and natural compounds enriched in platinum-group elements (PGE), which are associated with various complexes and deposits, such as Uralian-Alaskan-type complexes, layered intrusions and placers. The geographical locations of the involved deposits and complexes include, on a truly international scale, different areas of the Urals, Western and Eastern Sayans and Gornaya Shoria in Siberia, Southern Central Asian Orogenic Belt in China, Northern Michigan, USA, South Africa and Zimbabwe, etc. Of particular interest is the first description of a new species of PGM, thalhammerite (approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association), which is a new species of palladium-silver sulfobismuthide discovered in the Noril’sk region of Russia. Additionally, comprehensive reviews, on compositional variations in Pt–Fe alloy minerals and processes of transformations of PGM in exogenic environments, are presented which will also attract attention from international readers.

Keywords

platinum-group elements --- platinum-group minerals --- PGE alloys --- chromian spinel --- schemes of substitution --- Ti- and REE-rich inclusions --- Sisim placer zone --- Lysanskiy complex --- Eastern Sayans --- Russia --- platinum-group elements --- gold --- platinum-group minerals --- placer deposits --- ophiolite complexes --- western Sayans --- Russia --- thalhammerite --- platinum-group mineral --- Pd9Ag2Bi2S4 phase --- reflectance data --- X-ray-diffraction data --- crystal structure --- Komsomolsky mine --- Talnakh deposit --- Noril’sk region --- Russia --- chromitite --- platinum group minerals --- primary inclusions --- ophiolite --- Alaskan-type complex. --- Urals --- Russia --- Alaskan-type complex --- Central Asian Orogenic Belt --- PGM --- PGE mineralization --- Bushveld Complex --- South Africa --- Great Dyke --- Zimbabwe --- platinum-group minerals --- primary ores --- oxide ores --- placers --- allogenic --- authigenic --- Echo Lake --- Midcontinent --- palladium --- platinum --- magnetite --- gabbro --- platinum-group elements --- platinum-group minerals --- Pt–Fe alloys --- compositional variations --- element substitutions --- placer deposits --- ore mineralization --- ultramafic-mafic complexes --- Ural Platinum belt --- Ural-Alaskan massif --- Svetloborsky massif --- placer system --- platinum group elements --- platinum group minerals --- platiniferous tetra-auricupride --- Pt-for-Au substitution --- platinum --- gold --- ophiolite --- Bolshoy Khailyk placer --- western Sayans --- Russia --- platinum-group elements --- gold --- platinum-group minerals --- placer deposits --- micrometric inclusions --- Gornaya Shoria --- Siberia --- Russia --- n/a

Geomicrobiology and Biogeochemistry of Precious Metals

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ISBN: 9783038973461 9783038973478 Year: Pages: 182 DOI: 10.3390/books978-3-03897-347-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Biotechnology --- Ecology --- Geology --- Earth Sciences --- Environmental Sciences
Added to DOAB on : 2018-11-20 10:57:53
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Precious metals continue to have economic and sociocultural importance, as their usage evolves and diversifies over time. Today, the industrial application of precious metals is increasing with the development of scientific and technological innovations. Especially, the biological cycling of these metals is receiving more and more attention, as the microbiota may be key to a range of issues regarding exploration, ore-processing and metallurgy, and the processing of electron waste. In this volume, we focus on enhancing the fundamental understanding of the biological processes that drive noble metal cycling and examine how this knowledge may be turned into biotechnolical applications.

Unconventional Anticancer Metallodrugs and Strategies to Improve their Pharmacological Profile

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ISBN: 9783039213153 9783039213160 Year: Pages: 204 DOI: 10.3390/books978-3-03921-316-0 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Biology --- Biochemistry
Added to DOAB on : 2019-12-09 11:49:15
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For the past 40 years, metal-based drugs have been widely used for the treatment of cancer. Cisplatin and follow-up drugs carboplatin (ParaplatinTM) and oxaliplatin (EloxatinTM) have been the gold standard for metallodrugs in clinical settings as antineoplastic agents. While effective, these drugs (either alone or in combination therapy) have faced a number of clinical challenges resulting from their limited spectrum of activity, high toxicity leading to significant side effects, resistance, poor water solubility, low bioavailability and short circulating time. In the past 10 years, various unconventional non-platinum metal-based agents have emerged as a potential alternative for cancer treatment. These compounds are highly effective and selective in cancers resistant to cisplatin and other chemotherapeutic agents. Research in this area has recently exploded with a relevant number of patents and clinical trials, in addition to reports in scientific journals. Furthermore, in parallel to the synthesis of coordination and organometallic compounds comprising many different metals and unconventional platinum-based derivatives, researchers are focused on optimizing mechanistic and pharmacological features of promising drug candidates. This Special Issue aims to highlight the latest advances in anticancer metallodrugs with a focus on unconventional anticancer agents, as well as novel activation, targeting and delivery strategies aimed at improving their pharmacological profile.

Electrochemical Surface Science: Basics and Applications

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ISBN: 9783039216420 9783039216437 Year: Pages: 398 DOI: 10.3390/books978-3-03921-643-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-12-09 11:49:15
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Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.

Keywords

electrosynthesis --- switchable surfaces --- alkoxyamine surfaces --- redox monolayers --- porphyrins --- self-assembly --- surface nanostructures --- in situ EC-STM --- metal-electrolyte interface --- potential-dependent structures --- combined non-covalent control --- ECALE --- CdS --- silver single crystals --- alkanthiols --- SAMs --- EQCM --- AES --- polypyrrole --- diazonium salts --- flexible ITO --- adhesion --- redox properties --- X-ray absorption spectroscopy --- energy dispersive --- quick-XAS --- FEXRAV --- free electron laser --- electrochemistry --- photoelectrochemistry --- photochemistry --- pump &amp --- probe --- oxygen evolution reaction --- water splitting --- iridium --- thin-films --- spin-coating --- model systems --- electrocatalysts --- oxygen evolution reaction --- iridium --- nickel --- electrodeposition --- model catalyst --- water oxidation --- CO oxidation --- DFT --- hydrogen adsorption --- Pt–Ru catalysts --- ordered mesoporous carbons --- graphitization --- CO oxidation --- methanol oxidation --- direct methanol fuel cells --- electrocatalysis --- catalysts --- methanol oxidation reaction --- graphene --- DMFC --- Pt --- SOFC --- cathode --- XAFS --- in situ --- cobalt oxide --- water oxidation --- photo-electrochemistry --- hydroxyl radical --- electro-oxidation --- Lead OPD --- surface alloy --- XPS --- UPS --- EF-PEEM --- ORR --- Platinum --- PVDF --- PEMFC --- in situ ambient pressure XPS --- hard X rays --- photoelectron simulations --- solid/liquid interface --- TiO2 --- APTES --- Cu(111) --- electrochemical interface --- in-situ X-ray diffraction --- carbon nanofiber --- porous fiber --- electrospinning --- mesopore --- micropore --- porogen --- ammonia activation --- surface area --- methanol oxidation --- platinum single crystals --- pH and concentration effects --- adsorbed OH --- reduced graphene oxide --- electrophoretic deposition --- surface chemistry --- click chemistry --- gold --- palladium --- bimetallic alloy --- carbon nanofibers (CNFs) --- cyclic voltammetry (CV) --- Surface Modification --- Blackening of Steel --- Magnetite --- Corrosion Protection --- Auger-Electron Spectroscopy --- Ordered mesoporous carbon --- nitrogen doping --- cobalt-based electrocatalyst --- bifunctional oxygen electrode --- solvothermal method --- underpotential deposition (upd) --- Au --- Pt --- Pd --- nanoparticles --- cyclic voltammetry --- electrocatalysis --- operando --- near ambient pressure XPS --- scanning photoelectron microscopy --- solid oxide fuel cells --- surface science --- electrodeposited alloys --- CO electro-oxidation --- Pt single-crystal electrodes --- potential cycling --- potential stepping --- surface reconstruction --- electrocatalysis --- oxygen reduction --- ORR --- gas diffusion electrode --- platinum --- fuel cells --- thin-films --- benchmarking --- mass transport --- formic acid oxidation --- Au nanocrystals --- Pd thin films --- electrocatalysis --- d-band theory --- polymer --- silicon nanoparticles --- EPR spectroscopy --- photoconversion --- n/a

Design and Development of Nanostructured Thin Films

Authors: --- ---
ISBN: 9783039287383 / 9783039287390 Year: Pages: 386 DOI: 10.3390/books978-3-03928-739-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General)
Added to DOAB on : 2020-06-09 16:38:57
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Due to their unique size-dependent physicochemical properties, nanostructured thin films are used in a wide range of applications from smart coating and drug delivery to electrocatalysis and highly-sensitive sensors. Depending on the targeted application and the deposition technique, these materials have been designed and developed by tuning their atomic-molecular 2D- and/or 3D-aggregation, thickness, crystallinity, and porosity, having effects on their optical, mechanical, catalytic, and conductive properties. Several open questions remain about the impact of nanomaterial production and use on environment and health. Many efforts are currently being made not only to prevent nanotechnologies and nanomaterials from contributing to environmental pollution but also to design nanomaterials to support, control, and protect the environment. This Special Issue aims to cover the recent advances in designing nanostructured films focusing on environmental issues related to their fabrication processes (e.g., low power and low cost technologies, the use of environmentally friendly solvents), their precursors (e.g., waste-recycled, bio-based, biodegradable, and natural materials), their applications (e.g., controlled release of chemicals, mimicking of natural processes, and clean energy conversion and storage), and their use in monitoring environment pollution (e.g., sensors optically- or electrically-sensitive to pollutants)

Keywords

InAlN --- nanospiral --- metamaterial --- sputtering --- chirality --- microparticle deposition --- self-assembly --- homogeneity --- monomer synthesis --- mask --- hazardous organic solvents --- photonic nanostructures --- self-assembly --- polymer nanoparticles --- biomimetic solvent sensors --- iridescence --- mesoporous --- Al2O3 --- MgO --- poly(dimethylacrylamide) --- hydrogel --- thin film --- spin coating --- SEM --- FIB --- Kr physisorption --- hydrogenated amorphous carbon films --- metallic nanoparticles --- hybrid deposition system --- nanoscratch --- nanocomposites --- aqueous dispersion --- carbon nanotube --- graphene oxide --- ink --- rod coating --- electrical conductivity --- optical transmittance --- mechanical flexibility --- silk sericin --- agarose --- lysozyme --- composite gel --- wound dressing --- nanofiber --- lamination --- water filtration --- CdTe --- self-catalysed --- wires --- Mg alloy --- LDH --- corrosion --- deposition --- coating --- ReB2/TaN multilayers --- modulation structure --- first-principles calculation --- interfacial model --- adsorption energy --- interfacial energy --- biomaterial --- biomedical --- nanofibers --- scaffolds --- reinforced --- hybrid material --- thermal analysis --- nanofibrous membranes --- light trapping --- silicon thin film --- photovoltaics --- polystyrene sphere assisted lithography --- nanostructured back reflectors --- Raman scattering --- quantum confinement --- electron–phonon coupling --- polar semiconductors --- zinc oxide --- metal-organic framework --- microscopy --- thin films --- powders --- electrodeposition --- platinum --- highly oriented pyrolytic graphite --- 2D growth --- barrier material --- nanocoating of SiOx --- polymeric matrix --- plasma deposition --- PVD --- PA-PVD --- PECVD --- permeation --- CERAMIS® --- SorpTest --- iron oxides --- FeO --- Fe3O4 --- ultrathin films --- epitaxial growth --- platinum --- ruthenium --- symmetry --- LEEM --- LEED --- XPEEM --- electrodeposition --- platinum --- highly oriented pyrolytic graphite --- 2D growth --- thin films --- TiO2NPs --- AuNPs --- photocatalysis --- mercury vapors adsorbing layer --- PAS device --- iron oxides --- ultrathin films --- silver --- epitaxial growth --- structural characterization --- STM --- LEED --- XPS --- DFT --- model system --- Pt thin deposits --- galvanic displacement --- UPD --- SLRR --- electrocatalysis --- nanostructured films --- birefringence --- nanocrystalline cellulose --- Mueller matrix --- vanadium dioxide --- post-treatment --- plasma irradiation --- luminous transmittance --- phase transition performance --- electrospinning deposition --- chemosensor --- nanocomposite conductive polymers --- polyhydroxibutyrate --- polystyrene --- H2TPP --- VOCs selectivity --- mesoporous graphene --- thin film --- nanostructure --- CaxCoO2 --- sputtering --- phase transformation --- Ge surface engineering --- La2O3 passivation layer --- atomic layer deposition --- electrical properties

Advances in Hydrometallurgy

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ISBN: 9783039289394 / 9783039289400 Year: Pages: 188 DOI: 10.3390/books978-3-03928-940-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-06-09 16:38:57
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The development of new technologies and the increasing demand for mineral resources from emerging countries are responsible for significant tensions in the pricing of non-ferrous metals. Some metals have become strategic and critical because they are used in many technological applications such as flat panel TVs (indium), solar panel cells (indium), lithium-ion batteries for electric vehicles (lithium, cobalt), magnets (rare earth elements, such as neodymium and dysprosium), scintillators (rare earths), and aviation and medical applications (titanium); their availabilities remain limited. The secured supply of these metals is crucial to continue producing and exporting these technologies, and because the specific properties of these metals make them essential and difficult to substitute for a given industrial application. Hydrometallurgy have the advantages of being able to process low-grade ores, to allow better control of co-products, and have a lower environmental impact providing that the hydrometallurgical route is optimized and cheap. The need to develop sustainable, efficient, and cheap processes to extract metals from complex and poor polymetallic matrices is real. The aim of this book was to highlight recent advances related to hydrometallurgy to face new challenges in metal production.

Mineralogy of Noble Metals and “Invisible” Speciations of These Elements in Natural Systems

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ISBN: 9783039286348 / 9783039286355 Year: Pages: 224 DOI: 10.3390/books978-3-03928-635-5 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Geology --- Earth Sciences
Added to DOAB on : 2020-06-09 16:38:57
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This Special Issue covers a broad range of topics related to the mineralogy of noble metals (Au, Ag, Pt, Pd, Rh, and Ru) and the occurrence, formation, and distribution of these elements in natural ore-forming systems. This collection of eleven research articles discusses various problems related to these topics. I hope this Special Issue will contribute to a better understanding of the genesis of gold, silver, and other noble metal deposits as well as the behavior of these elements in endogenic and supergene environments, and suggest ways forward to solving the problem of their full extraction from ores.

Keywords

gold selenide --- gold sulfoselenide --- colloids --- nanoparticles --- nucleation --- liquid intermediates --- deposition --- XPS --- sulfide minerals --- platinum --- deposition --- valleriite --- chloride complexes --- zircon U–Pb age --- in situ sulfur isotopes --- gold source --- ore genesis --- Chaoyangzhai gold deposit --- Southeast Guizhou --- mineralization age --- Nibao gold deposit --- ore-forming fluid --- Rb–Sr isotopic composition --- Yunnan–Guizhou–Guangxi “Golden Triangle” region --- Gaching ore deposit --- mustard gold --- calaverite --- maletoyvayamite --- Fe-Sb(Te,As,Se,S)-oxides --- Au-Sb(Te,Se,S,As)-oxides --- Cu-Fe-Ni-S system --- platinum-group elements --- Au --- Ag --- metalloid elements --- fractional crystallization --- drop-shaped inclusions --- noble metals --- invisible species --- distribution --- pyrite --- arsenopyrite --- structural and surficial modes --- arsenopyrite --- crystal lattice --- ligand surroundings --- non-equal positions --- Mössbauer Effect --- gold --- “invisible” gold --- gold ore deposits --- Kagan ultramafic massif --- Southern Urals --- antigorite serpentinites --- magnetite veins --- gold mineralization --- native gold --- thermodynamic modeling --- fluid regime --- Fennoscandian Shield --- Kolmozero–Voronya belt --- Oleninskoe deposit --- mustard gold --- dyscrasite --- chlorargyrite --- gold ore field --- karst cavities --- monolithic and porous gold --- Tl oxides (avicennite) --- Tl carbonates --- Tl tellurates and antimonates --- n/a

Catalysis by Precious Metals, Past and Future

Authors: ---
ISBN: 9783039287222 / 9783039287239 Year: Pages: 204 DOI: 10.3390/books978-3-03928-723-9 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2020-06-09 16:38:57
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The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented.

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