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Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis

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Book Series: Beiträge zur organischen Synthese ISBN: 9783832550714 Year: Volume: 85 Pages: 226 DOI: 10.30819/5071
Publisher: Logos Verlag Berlin GmbH
Subject: Chemistry (General)
Added to DOAB on : 2020-09-28 15:00:25
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Coatings to Improve Optoelectronic Devices

ISBN: 9783039283347 / 9783039283354 Year: Pages: 172 DOI: 10.3390/books978-3-03928-335-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-06-09 16:38:57
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This selection is focused on coatings and films with applications in optoelectronics, such as photovoltaics, photocatalysis, and light-based sensors and phenomena. The studies investigate the optimal composition, crystalline structure, and morphology to deliver the different functionalities sought. Obtaining transparent p-type electrodes is challenging but extremely relevant in optoelectronics. Electric conduction mechanisms and the correlations with structure and doping are discussed. The important issue of the degradation pathways in perovskite-based solar cells and the possibilities offered by different types of coatings to encapsulate the devices as well as the beneficial effect of silica coating as an antireflection and antisoiling layer on well-established solar cells are discussed. New designs of nanoplasmonic films for chemical and biological molecule sensing are reviewed, such as the combination of metallic nanoparticles and nanostructured semiconductors and dispersing metallic or bi-metallic nanoparticles in CuO films. The impacts of structure, defects, and morphology on the photoactivated properties of WO3 films and on the shape memory behavior in Cu–Al–Ni thin films are discussed. Aggregated TiO2 nanoparticles on TiO2 layers are shown to enhance optical transmittance and confer a superhydrophilic characteristic. Finally, aspects of the fundamental characterization of thin films, Drude damping in thin films, and laser-induced deflection technique are discussed.

Photocalytic Coatings for Air-Purifying, Self-Cleaning and Antimicrobial Properties

ISBN: 9783038421382 9783038421375 Year: Pages: 212 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Added to DOAB on : 2016-05-10 11:58:41
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This Special Issue of Coatings is focused on the study of different photocatalyst-basedcoatings for developing self-cleaning, air-purifying and antibacterial properties. In this case, awide variety of photocatalysts (TiO2, Si-TiO2, TiO2−xNy, Ag-TiO2, Mo-TiO2, ZnO, SnO2-Ag,Nb2O5 and C60 fullerene) were evaluated towards the removal of different molecules.Similarly, substrates such as glass, silica, sapphire, polycarbonate, aluminium, stainless steel,concrete and mortar were included in this issue. This information certainly contributes to a betterunderstanding of the photocatalytic removal of different molecules (e.g., Escherichia coli,Staphylococcus aureus, resazuring, rhodamine B, methylene blue, Demeton-S, 2-chloroethylphenyl sulfide (CEPS) and NOx (NO and NO2)) and the coating technologies required forsuch performances. Based on these interesting results, I encourage you to read through thisSpecial Issue and use the valuable information provided therein to help us move forward inthe exciting area of photocatalytic coatings for developing air-purifying, self-cleaning, andantimicrobial properties.

Application of Photoactive Nanomaterials in Degradation of Pollutants

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ISBN: 9783039213818 9783039213825 Year: Pages: 134 DOI: 10.3390/books978-3-03921-382-5 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General)
Added to DOAB on : 2019-12-09 11:49:15
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Photoactive nanomaterials have been receiving increasing attention due to their potential application in the light-driven degradation of water and gas-phase pollutants. However, to exploit the great potential of photoactive materials and access their properties requires fine-tuning of their size/shape-dependent chemical–physical properties, and on the ability to integrate them in photoreactors or to deposit them onto large surfaces. Therefore, the synthetic approach as well as post-synthesis manipulation could strongly affect the final photocatalytic properties of the nanomaterial. The aim of the present Special Issue is to report on the most recent progress towards the application of photoactive nanomaterials and nanomaterial-based coatings in pollutant degradation, paying particular attention to cases close to real application: scalable synthetic approaches to nanocatalysts, preparation of nanocatalyst-based coatings, degradation of real pollutants and bacterial inactivation, and application in building materials.

Nanomaterials for Environmental Purification and Energy Conversion

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ISBN: 9783039218141 9783039218158 Year: Pages: 264 DOI: 10.3390/books978-3-03921-815-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering --- Environmental Engineering
Added to DOAB on : 2020-04-07 23:07:08
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The Special Issue, “Nanomaterials for Environmental Purification and Energy Conversion”, describes the significant and increasing role of nanomaterials in catalysis. It is believed that the most important factor for future human development could be to use nanomaterials (nanotechnology) to solve such critical issues facing humanity such as environment, water and energy. It should be also pointed out that properties of nanomaterials differ substantially from that of bulk materials of the same composition, resulting in high reactivity. Therefore, it creates new perspectives for the catalytic processes in the broad sense. This issue was mainly dedicated as a platform for the contributions from The Symposium on Nanomaterials for Environmental Purification and Energy Conversion (SNEPEC), which was held in Sapporo, Japan in winter 2018. Accordingly, this book compiles the current state-of-the-art of research in the area of novel photocatalysts and highlights current research directions in the fields of advanced oxidation technologies, material science and nanotechnology. Written by leading experts in the field of photochemistry and chemical engineering, a collection of 17 papers, including 16 research papers and one review, covers a broad range of topics focusing on the exceptional role of catalytic nanomaterials in solving environmental and energy problems of modern societies. The majority of papers present the importance of photocatalytic nanomaterials, especially for degradation of organic pollutants and inactivation of microorganisms, but there is also a strong representation of conventional catalysis, based on nanomaterials for important processes such as catalytic hydrogen production and organic synthesis.

Keywords

TiOF2 --- NaOH-modified TiOF2 --- network shape --- photocatalysis --- RhB --- chemical looping reforming of methane --- yttrium promoted oxygen carrier --- SBA-16 --- hydrogen production --- conductive cotton filter --- carbon nanotubes --- low-cost --- water purification --- gravity feed --- alcohols --- salicylic acid --- multiwalled carbon nanotubes --- synthesis gas --- titanium dioxide --- graphene --- photocatalysis --- visible light --- dyes --- Cu nanoparticles --- Cu/FTO nanocomposites --- H2 evolution --- visible light --- transfer efficiency --- chemical looping --- oxygen carrier --- hydrogen production --- narrow pore size distribution --- Fe2O3 dispersion --- texture modification --- photocatalytic reduction --- TiO2 --- anatase --- CO2 --- flue gas --- adsorption --- magnetic ZnO --- methylene blue --- photodegradation --- rectorite --- dimethyl carbonate --- carbon dioxide --- ceria nanowires --- oxygen vacancy --- Pt-Au --- XAFS --- BCLA --- zinc chromite --- photocatalysis activity --- oxalate --- humic acid --- photocatalysis --- CO2 reduction --- anatase --- polydopamine --- sensitization --- heterogeneous photocatalysis --- TiO2/Cu2O nanotubes --- anodization --- nanomaterials fabrication --- removal of microbiological pollutants --- photocatalysis --- nanocomposites --- heterojunction --- Cu2O --- urea --- polytriazine --- Z-scheme --- ionic liquids --- ionic liquid-assisted solvothermal reaction --- reaction time --- titanium dioxide --- heterogeneous photocatalysis --- visible light --- C/TiO2 --- photocatalysis --- solar radiation --- disinfection --- immobilized catalyst --- n/a

Titanium Dioxide Photocatalysis

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ISBN: 9783038976943 9783038976950 Year: Pages: 208 DOI: 10.3390/books978-3-03897-695-0 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General)
Added to DOAB on : 2019-06-26 08:44:06
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Although the seminal work of Fujishima et al. dates back to 1971, TiO2 still remains the most diffused and studied semiconductor, employed in photo-oxidation processes for cleantech (i.e., polluted water and air treatment), in solar fuel production (mainly hydrogen production by water photo splitting), and in Carbon Capture and Utilization (CCU) processes by CO2 photoreduction. The eleven articles, among them three reviews, in this book cover recent results and research trends of various aspects of titanium dioxide photocatalysis, with the chief aim of improving the final efficiency of TiO2-based materials. Strategies include doping, metal co-catalyst deposition, and the realization of composites with plasmonic materials, other semiconductors, and graphene. Photocatalysts with high efficiency and selectivity can be also obtained by controlling the precise crystal shape (and homogeneous size) and the organization in superstructures from ultrathin films to hierarchical nanostructures. Finally, the theoretical modeling of TiO2 nanoparticles is discussed and highlighted. The range of topics addressed in this book will stimulate the reader’s interest as well as provide a valuable source of information for researchers in academia and industry.

Polyoxometalates

ISBN: 9783038421610 9783038421627 Year: Pages: 254
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Added to DOAB on : 2016-05-12 11:55:09
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Synthesis and Applications of Nanomaterials for Photocatalysis and Electrocatalysis

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ISBN: 9783039288311 / 9783039288328 Year: Pages: 213 DOI: 10.3390/books978-3-03928-832-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2020-06-09 16:38:57
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Heterogeneous catalysis, exploiting photo- and electrochemical reactions, has expanded rapidly in recent decades, having undergone various developments, especially from both energetic and environmental points of view. Photocatalysis plays a pivotal role in such applications as water splitting and air/water remediation. Electrocatalysis can be found in a large array of research fields, including the development of electroanalytical sensors, wastewater treatment, and energy conversion devices (e.g., batteries, fuel and solar cells, etc.). Therefore, the fine control of the synthetic procedures, together with extensive physicochemical characterisations of the tailor-made catalytic nanomaterials, are of fundamental importance to achieving the desired results. The present book will include recent enhancements in oxide/metal nanoparticles for photocatalytic and electrocatalytic applications, especially in the fields of pollutants abatement and energy conversion.

Novel Photoactive Materials

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ISBN: 9783038976509 Year: Pages: 166 DOI: 10.3390/books978-3-03897-651-6 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Physics (General) --- Science (General)
Added to DOAB on : 2019-03-05 14:29:32
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Photoactivity represents the ability of a material, generally speaking a semiconductor, to become active when interacting with light. It can be declined in many ways, and several functionalities arising from this behavior of materials can be exploited, all leading to positive repercussions on our environment. There are several classes of effects of photoactivity, all of which have been deeply investigated in the last few decades, allowing to develop more and more efficient materials and devices. All of them share a common point, that is, the interaction of a material with light, although many different materials are taken into account depending on the effect desired—from elemental semiconductors like silicon, to more complex compounds like CdTe or GaAs, to metal oxides like TiO2 and ZnO. Given the broadness of the field, a huge number of works fall within this topic, and new areas of discovery are constantly explored. The special issue “Novel Photoactive Materials” has been proposed as a means to present recent developments in the field, and for this reason the articles included touch different aspects of photoactivity, from photocatalysis to photovoltaics to light emitting materials.

Catalytic, Photocatalytic and Electrocatalytic Processes for the Valorisation of CO2

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ISBN: 9783039217786 9783039217793 Year: Pages: 132 DOI: 10.3390/books978-3-03921-779-3 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General)
Added to DOAB on : 2019-12-09 11:49:16
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Increasing attention is being paid to the development of effective technologies for the sequestration of CO2 and its storage. Hopefully, this will result in processes that can lead to its valorisation as a chemical, e.g., for the regeneration of fuels, but also for the production of intermediates. These are usually energy demands and rather slow processes, requiring energy input and catalysts. Some examples are the innovative strategies for the hydrogenation, photoconversion, or electroreduction of carbon dioxide. This book collects original research papers, reviews, and commentaries focused on the challenges related to the valorisation and conversion of CO2.

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