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Deaktivierung --- Dieseloxidationskatalysator --- Hysterese --- Platin --- Palladium
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Zur Bewertung der Umweltrelevanz der Kfz-emittierten PGE (Pt, Pd, Rh) ist das Verständnis ihres Verhaltens im Boden von grundlegender Bedeutung.In dieser Arbeit wurde das Sorptionsverhalten wasserlöslicher PGE an fünf typischen Bodenmineralen (Mn/Fe-Oxide, Kaolinit, Feldspat, Kalk, Quarz) untersucht.
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Das Ziel dieser Arbeit war die Entwicklung eines kontinuierlichen MOCVS/MOCVD-Verfahrens zur Generierung und Funktionalisierung von gasgetragenen, nanoskaligen Partikeln bei atmosphärischen Bedingungen und dessen Anwendung auf die Herstellung von Siliziumdioxid geträgerten Palladiumkatalysatoren (Pd/SiO2).
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Palladium (Pd)-based membranes have received a great deal of attention from both academia and industry thanks to their ability to selectively separate hydrogen from gas streams. The integration of such membranes with appropriate catalysts in membrane reactors allows for hydrogen production with CO2 capture that can be applied in smaller bioenergy or combined heat and power (CHP) plants, as well as in large-scale power plants. Pd-based membranes are therefore regarded as a Key Enabling Technology (KET) to facilitate the transition towards a knowledge-based, low-carbon, and resource-efficient economy. This Special Issue of the journal Membranes on “Pd-based Membranes: Overview and Perspectives” contains nine peer-reviewed articles. Topics include manufacturing techniques, understanding of material phenomena, module and reactor design, novel applications, and demonstration efforts and industrial exploitation.
review --- palladium --- membrane --- Pd alloy --- electroless plating --- membrane reactor --- hydrogen separation --- hydrogen production --- MLLDP --- porous membrane --- pore mouth size distribution --- dense Pd membrane --- defect distribution --- methanol steam reforming --- hydrogen production --- modelling --- membrane reactors --- membrane --- hydrogen --- palladium alloy --- grain boundary --- chemical potential --- activity --- hydrides --- solubility --- membranes --- Pd-Ag membranes --- hydrogen permeation --- surface characterization --- solubility --- heat treatment --- Pd-based membrane --- hydrogen --- closed architecture --- open architecture --- gas to liquid --- propylene --- membrane reactor --- hydrogen --- palladium --- microstructured --- LOHC --- suspension plasma spraying --- LOHC --- dehydrogenation --- multi-stage --- PdAg-membrane --- micro reactor --- hydrogen purification --- palladium-based membrane --- hydrogen --- manufacturing --- demonstration
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The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented.
microwave --- catalyst synthesis --- Pt/Al2O3 --- aging --- platinum dispersion --- drying --- DOC --- hydrogenolysis --- glycerol --- 1-propanol --- 2-propanol --- palladium catalyst --- palladium catalysts --- CNTs --- dodecahydro-N-ethylcarbazole --- dehydrogenation --- hydrogen storage --- precious metals --- reduction temperature --- hydrodechlorination --- XPS --- dispersion --- turnover frequency --- gold nanoparticles --- clay --- PVA --- stabilizing agent --- glucose oxidation --- phenol photo-degradation --- CO oxidation --- Au–TiO2 --- gold catalysts --- titania --- sustainable ammonia synthesis --- ruthenium --- caesium --- porous carbons --- renewable hydrogen --- direct reduction --- propane dehydrogenation --- Pt–Sn/Al2O3 --- Pt3Sn alloy --- PtSn alloy --- P25@Pd --- core-shell --- heterogeneous enantioselective hydrogenation --- acetophenone --- palladium --- chelate --- amino acid --- proline --- N-methylproline --- azetidine --- pipecolinic acid --- 4-fluoroproline --- 4-hydroxyproline --- 2-?-benzylproline --- hydrogen bonding --- oxidative coupling --- X-ray crystallography --- perovskite --- photochemical --- photodegradation --- precious metals --- gas phase hydrogenation --- alkynols --- 3-butyn-1-ol --- 3-butyn-2-ol --- 2-methyl-3-butyn-2-ol --- alkenols --- triple bond electron charge --- Pd/Al2O3 --- n/a
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Through evolution of life, animals have adapted to the ubiquitous presence of metals in the biosphere. They utilize the more frequent ones as essential constituents of their biochemical machinery. In fact, about 40% of all proteins present in animal cells are so-called metalloproteins. On the other hand, animals have invented regulatory and detoxifying mechanisms to protect themselves from critical concentrations of both essential and non-essential metal concentrations. Metallomics is a modern approach applying cellular, biochemical, molecular and analytical methods to investigate the relationships of metals in their cellular context. The present edition contains a number of original articles and reviews dealing with various aspects of metallomics in animals, published as Special Issues of the International Journal of Molecular Sciences in 2016 and 2017. The book addresses subjects such as metal definition in biology, metabolism of metals in invertebrate and vertebrate animals, metal detoxification and regulation strategies, supplementation of essential trace elements, metal behavior in pregnancy and embryonic development, as well as metal toxicology and emerging medical implications.
Metal --- Essential Trace Element --- Metal Supplementation --- Non-Essential Trace Element --- Metal Toxicity --- Metal Uptake --- Phytochelatin --- Synthase --- Metallothionein --- Detoxification --- Accumulation --- Transgenic Organisms --- Regulation --- Homeostasis --- Metalloprotein --- Metalloenzyme --- Stress --- Oxidative Stress --- Apoptosis --- Protection --- Tolerance --- Immunity --- Allergy --- Hypersensitivity --- T Cells --- Development --- Cancer --- Model Organism --- Animal Model --- Molecular Methods --- Protein Biochemistry --- Binding Specificity --- Histology --- Protein Disease --- Cadmium --- Copper --- Zinc --- Iron --- Nickel --- Palladium --- Mercury --- Methylmercury
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In the last few decades, research on the elaboration by palladium-catalytic processes of C-C bonds or the activation of C–H bonds has increased considerably. Yet there is still room for much improvement in terms of selectivity, or enantioselectivity, via the development of new ligands or the study of the catalytic effect of other metals to carry out the same chemical transformations. In addition, the attention paid to environmentally friendly methods in terms of the quantities of catalysts, ligands, and solvents is currently indispensable. The Mizoroki-Heck reaction is one of these important catalytic methods which generates C-C bonds in organic synthesis and is also possible by C-H activation. This book, titled “Catalyzed Mizoroki-Heck Reaction or C-H activation” focuses on new advances in the formation of C-C bonds or new C-H activation methods. It contains original research papers and short reviews on the synthesis of biologically active compounds using these catalytic processes, the identification of new catalysts, of new conditions allowing selectivity or enantioselectivity, the activity and stability of catalyst under turnover conditions, and all improvements in catalytic processes.
Heck reaction --- reviews --- C-C coupling --- catalysis --- mechanism --- application --- Mizoroki-Heck reaction --- Pd-catalyzed --- fluorine --- cross-coupling --- alkenes --- halides --- enantioselective C–H activation --- C–C cross-coupling --- Suzuki reaction --- Mizoroki-Heck reaction --- Mizoroki-Heck --- abscisic acid --- solvent-free --- C–C bond formation --- Henry reaction --- solid base catalyst --- layered double hydroxide --- C–H activation --- regioselectivity --- thienopyridines --- thienopyrimidines --- thienopyrazines --- C-H activation --- palladium --- alkoxylation --- dihydrobenzo[c]acridine --- n/a
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This Special Issue is aimed at highlighting the potentialities of membrane and membrane reactor operations in various sectors of chemical engineering, based on application of the process intensification strategy. In all of the contributions, the principles of process intensification were pursued during the adoption of membrane technology, demonstrating how it may lead to the development of redesigned processes that are more compact and efficient while also being more environmental friendly, energy saving, and amenable to integration with other green processes. This Special Issue comprises a number of experimental and theoretical studies dealing with the application of membrane and membrane reactor technology in various scientific fields of chemical engineering, such as membrane distillation for wastewater treatment, hydrogen production from reforming reactions via inorganic membrane and membrane photoassisted reactors, membrane desalination, gas/liquid phase membrane separation of CO2, and membrane filtration for the recovery of antioxidants from agricultural byproducts, contributing to valorization of the potentialities of membrane operations.
membrane engineering --- hydrogen production --- CO2 conversion --- gas/liquid separation --- micro direct methanol fuel cell (µDMFC) --- porous membranes --- micro channel --- two-phase flow --- micro contactor --- separator --- water splitting --- Z-scheme --- photocatalysis --- photocatalytic membrane reactor --- hydrogen --- on-board --- steam reforming --- ethanol --- methane --- membrane reactor --- palladium --- modeling --- membrane distillation --- wastewater treatment --- membrane configuration --- fouling renewable heat sources --- membrane reactor --- Pd-based membrane --- hydrogen --- steam reforming --- solar energy --- microfiltration (MF) --- ultrafiltration (UF) --- orange press liquor --- clarification --- multivariate analysis --- advanced separations --- desalination --- hydrogel composite membranes --- ionic liquids membranes --- membrane distillation
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Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.
hydrogenation --- copper --- catalyst --- water --- deactivation --- octanal --- octanol --- V2O5–WO3/TiO2 catalysts --- poisoning --- sulfur-containing sodium salts --- SO3 --- NO removal --- Cu/SSZ-13 --- NH3-SCR --- sodium ions --- deactivation mechanism --- sulfur poisoning --- coke deposition --- in situ regeneration --- Co-Zn/H-Beta --- NOx reduction by C3H8 --- catalyst deactivation --- diesel --- natural gas --- SEM --- TEM --- poisoning --- oxygen storage capacity --- thermal stability --- cyclic operation --- deactivation --- oxysulfate --- oxysulfide --- Selective Catalytic Reduction (SCR) --- SO2 poisoning --- Low-temperature catalyst --- nitrogen oxides --- nitrous oxide --- dry reforming of methane --- nickel catalysts --- barium carbonate --- deactivation by coking --- catalytic methane combustion --- exhaust gas --- catalyst durability --- Liquefied natural gas --- biogas --- vehicle emission control --- sulfur deactivation --- catalyst deactivation --- aluminum sulfate --- palladium sulfate --- regeneration --- phthalic anhydride --- vanadia-titania catalyst --- unusual deactivation --- physico-chemical characterization --- over-reduction --- vanadia species --- coke deposition --- DeNOx --- MW incinerator --- deactivation --- ammonium sulfates --- regeneration --- washing --- CO2 reforming --- Ni-catalyst --- syngas --- tetragonal zirconia --- phase stabilization --- CPO reactor --- effect of flow rate --- deactivation --- iso-octane --- Rh catalysts --- Rh --- homogeneous catalysis --- catalyst deactivation --- n/a
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Nanomaterials possess astonishing physical and chemical properties. They play a key role in the development of novel and effective drugs, catalysts, sensors, and pesticides, to cite just a few examples. Notably, the synthesis of nanomaterials is usually achieved with chemical and physical methods needing the use of extremely toxic chemicals or high-energy inputs. To move towards more eco-friendly processes, researchers have recently focused on so-called “green synthesis”, where microbial, animal-, and plant-borne compounds can be used as cheap reducing and stabilizing agents to fabricate nanomaterials. Green synthesis routes are cheap, environmentally sustainable, and can lead to the fabrication of nano-objects with controlled sizes and shapes—two key features determining their bioactivity.
solvothermal synthesis --- CuInS2 --- TEM --- nanomaterials (NMs) --- nanostructured --- synthetic amorphous silica (SAS) --- ultrasonic dispersing (USD) --- energy density --- sample preparation --- in vitro testing --- green synthesis --- cacao --- non-cytotoxic --- Scadoxus multiflorus --- leaf --- ZnO NPs --- larvicidal --- ovicidal --- anti-fungal --- mesoporous materials --- carbon spheres --- hollow carbon spheres --- solid carbon spheres --- CVD process --- time dependence --- titanium dioxide nanoparticles --- green synthesis --- gum kondagogu --- methylene blue --- photocatalysis --- polyol-assisted fluoride ions slow-release strategy --- NaYF4 mesocrystals --- crystallographic phase control --- chitosan --- poly-L-lactic acid --- plasma --- silver nanoparticles --- antimicrobial --- hybrid nanoflowers --- lipase --- magnetic nanomaterials --- biocatalysis --- enzyme immobilization --- palladium nanoparticles --- microwave injured cells --- microwave energy --- Escherichia coli --- Desulfovibrio desulfuricans --- graphene oxide --- reduced graphene oxide --- X-ray photoelectron spectroscopy --- Raman spectroscopy --- electrical conductivity --- functionalization --- self-assembly --- sponges --- ionic nanocomplexes --- polyarginine --- hyaluronic acid --- cell proliferation --- n/a --- agricultural pests --- dengue --- filariasis --- insecticides --- larvicides --- mosquito control --- stored product insects
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