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Extrusion von technischen ZSM-5-Kontakten und ihre Anwendung im MTO-Prozess

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ISBN: 9783866444102 Year: Pages: 176 S DOI: 10.5445/KSP/1000012268 Language: GERMAN
Publisher: KIT Scientific Publishing
Subject: Chemical Engineering
Added to DOAB on : 2019-07-30 20:01:57
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In dieser Arbeit wurden technische Zeolithkatalysatoren (ZSM-5 + Binder) mittels Extrusion hergestellt und im Festbett-MTO-Prozess (Methanol-to-Olefins) getestet. Das Ziel war die Optimierung der Reaktionsbedingungen und des Katalysators, um möglichst hohe Selektivitäten zu Ethen und Propen sowie verbesserte Katalysatorstandzeiten zu erreichen.

Zum Stofftransport in Brennstoffzellenmembranen : Untersuchungen mit Hilfe der konfokalen Mikro-Raman-Spektroskopie

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ISBN: 9783866444324 Year: Pages: VIII, 154 p. DOI: 10.5445/KSP/1000013170 Language: GERMAN
Publisher: KIT Scientific Publishing
Subject: Chemical Engineering
Added to DOAB on : 2019-07-30 20:01:59
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Im Rahmen dieser Arbeit wurde die Pervaporation von Wasser und Alkohol durch Direkt-Alkohol-Brennstoffzellenmembranen aus Nafion mit Hilfe der konfokalen Mikro-Raman-Spektroskopie untersucht. Durch den Vergleich von gemessenen Beladungsprofilen mit Simulationsrechnungen wurden bei unterschiedlichen Pervaporationsraten Diffusionskoeffizienten und Phasengleichgewichtsdaten bestimmt.

Plant cell wall in pathogenesis, parasitism and symbiosis

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Book Series: Frontiers Research Topics ISSN: 16648714 ISBN: 9782889194421 Year: Pages: 150 DOI: 10.3389/978-2-88919-442-1 Language: English
Publisher: Frontiers Media SA
Subject: Botany --- Science (General)
Added to DOAB on : 2016-02-05 17:24:33
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The cell wall is a complex structure mainly composed of cellulose microfibrils embedded in a cohesive hemicellulose and pectin matrix. Cell wall structural proteins, enzymes and their inhibitors are also essential components of plant cell walls. They are involved in the cross-link of cell wall polysaccharides, wall structure, and the perception and signaling of defense-related elicitors at the cell surface. In the outer part of the epidermal cells, the polysaccharides are coated by the cuticle, consisting of hydrophobic cutin, suberin and wax layers. Lignin, a macromolecule composed of highly cross-linked phenolic molecules, is a major component of the secondary cell wall. The cell wall is the first cell structure on which interactions between plants and a wide range of other organisms, including insects, nematodes, pathogenic or symbiotic micro-organisms take place. It not only represents a barrier that limits access to the cellular contents that provide a rich nutrient source for pathogens but serves as a source of elicitors of plant defense responses released upon partial enzymatic degradation of wall polysaccharides during infection. Modification of the plant cell wall can also occur at the level of plasmodesmata during virus infection as well as during abiotic stresses. The fine structure and composition of the plant cell wall as well as the regulation of its biosynthesis can thus strongly influence resistance and susceptibility to pathogens. This Research Topic provides novel insights and detailed overviews on the dynamics of the plant cell wall in plant defence, parasitism and symbiosis and describes experimental approaches to study plant cell wall modifications occurring during interaction of plants with different organisms.

Electrocatalysis in Fuel Cells

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ISBN: 9783038422341 9783038422198 Year: Pages: XXX, 658 DOI: 10.3390/books978-3-03842-219-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Added to DOAB on : 2016-07-12 11:10:02
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Advances in Catalyst Deactivation

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ISBN: 9783038421870 9783038421887 Year: Pages: X, 300 DOI: 10.3390/books978-3-03842-188-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemical Engineering
Added to DOAB on : 2016-06-07 11:25:06
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Catalyst deactivation, the loss over time of catalytic activity and/or selectivity, is a problem of great and continuing concern in the practice of industrial catalytic processes. Costs to industry for catalyst replacement and process shutdown total tens of billions of dollars per year. While catalyst deactivation is inevitable for most processes, some of its immediate, drastic consequences may be avoided, postponed, or even reversed. Accordingly, there is considerable motivation to better understand catalyst decay and regeneration. Indeed, the science of catalyst deactivation and regeneration has been developing rapidly as evidenced by the considerable literature addressing this topic, including 21,000 journal articles, presentations, reports, reviews, and books; and more than 29,000 patents for the period of 1980 to 2012. This developing science provides the foundation for continuing, substantial improvements in the efficiency and economics of catalytic processes through development of catalyst deactivation models, more stable catalysts, and regeneration processes.This special issue focuses on recent advances in catalyst deactivation and regeneration, including advances in (1) scientific understanding of mechanisms; (2) development of improved methods and tools for investigation; and (3) more robust models of deactivation and regeneration.

Alternative Fuels for Transportation

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ISBN: 9781439819586 Year: Pages: 463 DOI: 10.1201/b16260 Language: English
Publisher: Taylor & Francis
Subject: Mathematics --- Heat --- Agriculture (General) --- Environmental Technology
Added to DOAB on : 2020-09-23 00:07:14
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Exploring how to counteract the world's energy insecurity and environmental pollution, this volume covers the production methods, properties, storage, engine tests, system modification, transportation and distribution, economics, safety aspects, applications, and material compatibility of alternative fuels. The esteemed editor highlights the importance of moving toward alternative fuels and the problems and environmental impact of depending on petroleum products. Each self-contained chapter focuses on a particular fuel source, including vegetable oils, biodiesel, methanol, ethanol, dimethyl ether, liquefied petroleum gas, natural gas, hydrogen, electric, fuel cells, and fuel from nonfood crops.

Electrochemical Surface Science: Basics and Applications

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ISBN: 9783039216420 9783039216437 Year: Pages: 398 DOI: 10.3390/books978-3-03921-643-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-12-09 11:49:15
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Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.

Keywords

electrosynthesis --- switchable surfaces --- alkoxyamine surfaces --- redox monolayers --- porphyrins --- self-assembly --- surface nanostructures --- in situ EC-STM --- metal-electrolyte interface --- potential-dependent structures --- combined non-covalent control --- ECALE --- CdS --- silver single crystals --- alkanthiols --- SAMs --- EQCM --- AES --- polypyrrole --- diazonium salts --- flexible ITO --- adhesion --- redox properties --- X-ray absorption spectroscopy --- energy dispersive --- quick-XAS --- FEXRAV --- free electron laser --- electrochemistry --- photoelectrochemistry --- photochemistry --- pump &amp --- probe --- oxygen evolution reaction --- water splitting --- iridium --- thin-films --- spin-coating --- model systems --- electrocatalysts --- oxygen evolution reaction --- iridium --- nickel --- electrodeposition --- model catalyst --- water oxidation --- CO oxidation --- DFT --- hydrogen adsorption --- Pt–Ru catalysts --- ordered mesoporous carbons --- graphitization --- CO oxidation --- methanol oxidation --- direct methanol fuel cells --- electrocatalysis --- catalysts --- methanol oxidation reaction --- graphene --- DMFC --- Pt --- SOFC --- cathode --- XAFS --- in situ --- cobalt oxide --- water oxidation --- photo-electrochemistry --- hydroxyl radical --- electro-oxidation --- Lead OPD --- surface alloy --- XPS --- UPS --- EF-PEEM --- ORR --- Platinum --- PVDF --- PEMFC --- in situ ambient pressure XPS --- hard X rays --- photoelectron simulations --- solid/liquid interface --- TiO2 --- APTES --- Cu(111) --- electrochemical interface --- in-situ X-ray diffraction --- carbon nanofiber --- porous fiber --- electrospinning --- mesopore --- micropore --- porogen --- ammonia activation --- surface area --- methanol oxidation --- platinum single crystals --- pH and concentration effects --- adsorbed OH --- reduced graphene oxide --- electrophoretic deposition --- surface chemistry --- click chemistry --- gold --- palladium --- bimetallic alloy --- carbon nanofibers (CNFs) --- cyclic voltammetry (CV) --- Surface Modification --- Blackening of Steel --- Magnetite --- Corrosion Protection --- Auger-Electron Spectroscopy --- Ordered mesoporous carbon --- nitrogen doping --- cobalt-based electrocatalyst --- bifunctional oxygen electrode --- solvothermal method --- underpotential deposition (upd) --- Au --- Pt --- Pd --- nanoparticles --- cyclic voltammetry --- electrocatalysis --- operando --- near ambient pressure XPS --- scanning photoelectron microscopy --- solid oxide fuel cells --- surface science --- electrodeposited alloys --- CO electro-oxidation --- Pt single-crystal electrodes --- potential cycling --- potential stepping --- surface reconstruction --- electrocatalysis --- oxygen reduction --- ORR --- gas diffusion electrode --- platinum --- fuel cells --- thin-films --- benchmarking --- mass transport --- formic acid oxidation --- Au nanocrystals --- Pd thin films --- electrocatalysis --- d-band theory --- polymer --- silicon nanoparticles --- EPR spectroscopy --- photoconversion --- n/a

Pd-based Membranes. Overview and Perspectives

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ISBN: 9783038977025 Year: Pages: 190 DOI: 10.3390/books978-3-03897-703-2 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemical Engineering --- Technology (General)
Added to DOAB on : 2019-04-05 10:34:31
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Palladium (Pd)-based membranes have received a great deal of attention from both academia and industry thanks to their ability to selectively separate hydrogen from gas streams. The integration of such membranes with appropriate catalysts in membrane reactors allows for hydrogen production with CO2 capture that can be applied in smaller bioenergy or combined heat and power (CHP) plants, as well as in large-scale power plants. Pd-based membranes are therefore regarded as a Key Enabling Technology (KET) to facilitate the transition towards a knowledge-based, low-carbon, and resource-efficient economy. This Special Issue of the journal Membranes on “Pd-based Membranes: Overview and Perspectives” contains nine peer-reviewed articles. Topics include manufacturing techniques, understanding of material phenomena, module and reactor design, novel applications, and demonstration efforts and industrial exploitation.

Membrane and Membrane Reactors Operations in Chemical Engineering

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ISBN: 9783039210220 9783039210237 Year: Pages: 154 DOI: 10.3390/books978-3-03921-023-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering --- Environmental Engineering
Added to DOAB on : 2019-06-26 10:09:00
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This Special Issue is aimed at highlighting the potentialities of membrane and membrane reactor operations in various sectors of chemical engineering, based on application of the process intensification strategy. In all of the contributions, the principles of process intensification were pursued during the adoption of membrane technology, demonstrating how it may lead to the development of redesigned processes that are more compact and efficient while also being more environmental friendly, energy saving, and amenable to integration with other green processes. This Special Issue comprises a number of experimental and theoretical studies dealing with the application of membrane and membrane reactor technology in various scientific fields of chemical engineering, such as membrane distillation for wastewater treatment, hydrogen production from reforming reactions via inorganic membrane and membrane photoassisted reactors, membrane desalination, gas/liquid phase membrane separation of CO2, and membrane filtration for the recovery of antioxidants from agricultural byproducts, contributing to valorization of the potentialities of membrane operations.

Multiscale and Innovative Kinetic Approaches in Heterogeneous Catalysis

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ISBN: 9783039211791 9783039211807 Year: Pages: 214 DOI: 10.3390/books978-3-03921-180-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-08-28 11:21:27
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Kinetics and reactor modeling for heterogeneous catalytic reactions are prominent tools for investigating and understanding catalyst functionalities at nanoscale and the related rates of complex reaction networks. This book illustrates some examples related to the transformation of simple to more complex feedstocks, including different types of reactor designs, i.e., steady-state, transient plug flow reactors, and TAP reactors for which there is sometimes a strong gap in the operating conditions from ultra-high-vacuum to high-pressure conditions. In conjunction, new methodologies have emerged, giving rise to more robust microkinetics models. As exemplified, they include the kinetics and the dynamics of the reactors and span a large range of length and time scales. The objective of this Special Issue is to provide contributions that can illustrate recent advances and novel methodologies for elucidating the kinetics of heterogeneous reactions and the necessary multiscale approach for optimizing the reactor design. This book is dedicated to postgraduate and scientific researchers, and experts in heterogeneous catalysis. It may also serve as a source of original information for the elaboration of lessons on catalysis for Master students.

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