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Catalyzed Mizoroki–Heck Reaction or C–H activation

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ISBN: 9783039281381 9783039281398 Year: Pages: 182 DOI: 10.3390/books978-3-03928-139-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Biology --- Science (General)
Added to DOAB on : 2020-04-07 23:07:08
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In the last few decades, research on the elaboration by palladium-catalytic processes of C-C bonds or the activation of C–H bonds has increased considerably. Yet there is still room for much improvement in terms of selectivity, or enantioselectivity, via the development of new ligands or the study of the catalytic effect of other metals to carry out the same chemical transformations. In addition, the attention paid to environmentally friendly methods in terms of the quantities of catalysts, ligands, and solvents is currently indispensable. The Mizoroki-Heck reaction is one of these important catalytic methods which generates C-C bonds in organic synthesis and is also possible by C-H activation. This book, titled “Catalyzed Mizoroki-Heck Reaction or C-H activation” focuses on new advances in the formation of C-C bonds or new C-H activation methods. It contains original research papers and short reviews on the synthesis of biologically active compounds using these catalytic processes, the identification of new catalysts, of new conditions allowing selectivity or enantioselectivity, the activity and stability of catalyst under turnover conditions, and all improvements in catalytic processes.

Novel Non-Precious Metal Electrocatalysts for Oxygen Electrode Reactions

Authors: --- ---
ISBN: 9783039215409 9783039215416 Year: Pages: 190 DOI: 10.3390/books978-3-03921-541-6 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-12-09 11:49:16
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Research on alternative energy harvesting technologies, conversion and storage systems with high efficiency, cost-effective and environmentally friendly systems, such as fuel cells, rechargeable metal-air batteries, unitized regenerative cells, and water electrolyzers has been stimulated by the global demand on energy. The conversion between oxygen and water plays a key step in the development of oxygen electrodes: oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), processes activated mostly by precious metals, like platinum. Their scarcity, their prohibitive cost, and declining activity greatly hamper large-scale applications. This issue reports on novel non-precious metal electrocatalysts based on the innovative design in chemical compositions, structure, and morphology, and supports for the oxygen reaction.

The Origin and Early Evolution of Life: Prebiotic Chemistry of Biomolecules

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ISBN: 9783039216062 9783039216079 Year: Pages: 288 DOI: 10.3390/books978-3-03921-607-9 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General)
Added to DOAB on : 2019-12-09 11:49:16
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Studying the origin of life is one of man’s greatest achievements over the last sixty years. The fields of interest encompassed by this quest are multiple and interdisciplinary: chemistry, physics, biology, biochemistry, mathematics, geology but also statistics, atmospheric science, meteorology, oceanography, and astrophysics. Recent scientific discoveries, such as water on Mars and the existence of super-Earths with atmospheres similar to primordial Earth, have pushed researchers to simulate prebiotic conditions in explaining the abiotic formation of molecules essential to life. This collection of articles offers an overview of recent discoveries in the field of prebiotic chemistry of biomolecules, their formation and selection, and the evolution of complex chemical systems.

Keywords

origin of life --- systems chemistry --- Chemomimesis --- Molecular Darwinism --- origin of life --- prebiotic chemistry --- thiol-rich peptides --- cysteine --- aminonitriles --- imidazoles --- origin of life --- prebiotic chemistry --- nucleotide and nucleoside synthesis --- protein design --- novel metalloproteins --- binary patterned amino acid sequences --- prebiotic chemistry --- population growth --- replication --- growth order --- Darwinian evolution --- selection --- origin of life --- abiogenesis --- carbon fixation --- hydrothermal vents --- electrochemistry --- reduction --- digit multiplicity --- information --- transmission --- encoding --- translation --- diversity --- function --- origin of life --- layered double hydroxide (LDH) clay --- pentose diphosphate --- pentopyranose nucleic acid --- arabinopyranose nucleic acid --- RNA --- base pairing --- purine precursor --- inosine --- AICAR --- peptide/RNA world --- prebiotic information system --- translation and the genetic code --- bridge peptide and aaRS --- ribozyme and tRNA --- tRNA and mRNA --- coevolution of translation machine and the genetic code --- MVC architecture pattern and biological information --- numerical codons --- AnyLogic software for computer simulation of translation machine --- phosphoryl transfer --- metabolism --- energy currency --- mixed anhydride --- origin of life --- hypercycle --- Monte Carlo --- prebiotic chemistry --- carbamic acid --- carbon dioxide-ammonia ices --- infrared spectra --- anharmonicity --- origin of life --- metabolism --- phosphates --- network expansion simulation --- thermodynamic bottleneck --- molecular clocks --- ab initio molecular dynamics --- catalysis --- prebiotic soup --- origins of life --- aldol reaction --- mechanochemistry --- minerals --- monosaccharides --- prebiotic chemistry --- prebiotic polymerization --- nucleotide oligomerization --- abasic oligomers --- nucleotide stability --- stability as a selection pressure --- dry-wet cycles --- genetic code origin --- tRNA accretion model --- tRNA-synthetase --- metabolism --- thioester --- nucleotidyltransferases --- early peptides --- ribosome --- n/a

Environment-Friendly Construction Materials

Authors: --- --- ---
ISBN: 9783039210121 9783039210138 Year: Pages: 280 DOI: 10.3390/books978-3-03921-013-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-06-26 08:44:06
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Construction materials are the most widely used materials for civil infrastructure in our daily lives. However, from an environmental point of view, they consume a huge amount of natural resources and generate the majority of greenhouse gasses. Therefore, many new and novel technologies for designing environmentally friendly construction materials have been developed recently. This Special Issue, “Environment-Friendly Construction Materials”, has been proposed and organized as a means to present recent developments in the field of construction materials. It covers a wide range of selected topics on construction materials.

Keywords

Ca-alginate microcapsules --- microfluidic --- self-healing --- bitumen --- mineral-asphalt mixtures --- aggregate from sanitary ceramic wastes --- environmentally friendly construction materials --- diatomite --- styrene–butadiene–styrene (SBS) modified bitumen --- diatomite-modified asphalt mixture --- road engineering --- fatigue life --- three-point bending fatigue test --- asphalt mixture --- plateau value of permanent deformation ratio --- damage evolution --- fatigue equation --- ultraviolet radiation --- bitumen --- aging depth --- transmittance --- permeation --- expanded graphite --- polyethylene glycol --- phase change materials --- titanate coupling agent --- molecular bridge --- building envelopes --- thermal property --- building energy conservation --- reclaimed asphalt pavement --- recycling --- epoxidized soybean oil --- rejuvenator --- diffusing --- asphalt pavement --- fatigue property --- pavement failure --- long-term field service --- asphalt mixture --- microwave heating --- induction heating --- effective heating depth --- induced healing --- initial self-healing temperature --- asphalt mastic --- flow behavior index --- steel slag --- limestone --- aggregate morphology --- aggregate image measurement system --- micro-surfacing --- skid-resistance --- surface texture --- asphalt --- water solute exposure --- aqueous solute compositions --- chemical evolutions --- rheological properties --- polyacrylic acid --- fluidity --- rheology --- adsorption --- combination --- cement emulsified asphalt mixture --- fatigue performance --- thickness combinations --- X-ray computed tomography --- artificial neural network --- crumb rubber --- high-strength concrete --- damping --- dynamic moduli --- railway application --- recycled material --- recycling --- sanitary ceramics --- concrete --- recycling aggregate --- asphalt mixture --- basalt fiber --- response surface methodology --- design optimization --- fluorescence spectrum --- bitumen --- ageing --- parametrization --- “blue-shift” --- asphalt --- asphalt mortar --- healing agents --- crack healing --- healing model --- ultra-thin wearing course --- self-healing --- induction heating --- steel fiber --- steel slag --- rankinite --- carbonation --- waste concrete --- CO2 --- aged bitumen --- rejuvenator --- solubilizer --- colloidal structure --- micro-morphology --- granite aggregate --- desulphurization gypsum residues --- rubber modified asphalt --- asphalt mixture --- pavement performance --- limestone aggregates --- emulsified asphalt --- demulsification speed --- surface energy --- specific surface area --- artificially aged asphalt mixture --- rejuvenator --- durability --- dynamic characteristics --- overlay tester --- energy-based approach --- dissipated strain energy --- plateau value of dissipated strain energy ratio --- fatigue life --- three-point bending fatigue test --- amorphous silica --- crystallization sensitivity --- water-leaching pretreatment --- rice husk ash --- cement --- crumb rubber --- anti-rutting agent --- flexibility --- field evaluation --- asphalt mixes --- aggregate characteristics --- simplex lattice design --- viscoelastic properties --- asphalt combustion --- flame retardant --- aluminum hydroxide --- layered double hydroxide --- asphalt mixture --- viscoelastic properties --- creep --- relaxation --- aggregates --- morphology --- crumb rubber powder --- SBS/CRP-modified bitumen --- aging processes --- temperature sensitivity characteristics --- diatomite --- basalt fiber --- asphalt mixture --- low-temperature --- damage constitutive model --- graphene --- nitrogen and phosphorus removal --- MDA --- SOD --- sequencing batch Chlorella reactor --- SEM --- thermal–mechanical properties --- bio-oil --- regeneration --- aged asphalt --- molecular dynamic simulation --- viscoelasticity --- nanomaterial --- hydrophobic nanosilica --- hydrophilic nanosilica --- laboratory evaluation --- diatomite --- basalt fiber --- compound modify --- asphalt mixture --- asphalt mixture --- basalt fiber --- freeze-thaw cycle --- damage characteristics --- high-modulus asphalt mixture (HMAM) --- dynamic tests --- viscoelasticity --- dynamic responses --- resistance to deformations --- tensile strains --- tensile stresses --- sensitivity analysis --- hot mix asphalt containing recycled concrete aggregate --- contact angle --- adhesion energy --- water stability --- fatigue performance --- self-compacting concrete (SCC) --- rheology --- workability --- pozzolanic reaction --- microstructure --- Ultra-High Performance Concrete (UHPC) --- long-term drying shrinkage --- hydration characteristic --- porous pumice --- optimization --- engineered cementitious composites (ECC) --- polyvinyl alcohol --- fiber modification --- mechanical behavior --- self-healing --- asphalt --- rejuvenation --- calcium alginate capsules --- asphalt-aggregate adhesion --- plant ash lixivium --- stripping test --- contact angle --- interfacial transition zone --- SBS-modified bitumen --- rejuvenating systems --- physical properties --- viscous-elastic temperature --- rutting factor --- vibration noise consumption --- cold recycled asphalt mixture --- reclaimed asphalt pavement --- mastic --- rheological properties --- emulsified asphalt --- cement --- construction materials --- fatigue life --- ageing resistance --- modified asphalt materials --- rejuvenator --- self-healing asphalt --- recycling --- cold recycled asphalt mixture --- ultra-high performance concrete

Environment-Friendly Construction Materials

Authors: --- --- ---
ISBN: 9783039210145 9783039210152 Year: Pages: 256 DOI: 10.3390/books978-3-03921-015-2 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-06-26 08:44:06
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Abstract

Construction materials are the most widely used materials for civil infrastructure in our daily lives. However, from an environmental point of view, they consume a huge amount of natural resources and generate the majority of greenhouse gasses. Therefore, many new and novel technologies for designing environmentally friendly construction materials have been developed recently. This Special Issue, “Environment-Friendly Construction Materials”, has been proposed and organized as a means to present recent developments in the field of construction materials. It covers a wide range of selected topics on construction materials.

Keywords

Ca-alginate microcapsules --- microfluidic --- self-healing --- bitumen --- mineral-asphalt mixtures --- aggregate from sanitary ceramic wastes --- environmentally friendly construction materials --- diatomite --- styrene–butadiene–styrene (SBS) modified bitumen --- diatomite-modified asphalt mixture --- road engineering --- fatigue life --- three-point bending fatigue test --- asphalt mixture --- plateau value of permanent deformation ratio --- damage evolution --- fatigue equation --- ultraviolet radiation --- bitumen --- aging depth --- transmittance --- permeation --- expanded graphite --- polyethylene glycol --- phase change materials --- titanate coupling agent --- molecular bridge --- building envelopes --- thermal property --- building energy conservation --- reclaimed asphalt pavement --- recycling --- epoxidized soybean oil --- rejuvenator --- diffusing --- asphalt pavement --- fatigue property --- pavement failure --- long-term field service --- asphalt mixture --- microwave heating --- induction heating --- effective heating depth --- induced healing --- initial self-healing temperature --- asphalt mastic --- flow behavior index --- steel slag --- limestone --- aggregate morphology --- aggregate image measurement system --- micro-surfacing --- skid-resistance --- surface texture --- asphalt --- water solute exposure --- aqueous solute compositions --- chemical evolutions --- rheological properties --- polyacrylic acid --- fluidity --- rheology --- adsorption --- combination --- cement emulsified asphalt mixture --- fatigue performance --- thickness combinations --- X-ray computed tomography --- artificial neural network --- crumb rubber --- high-strength concrete --- damping --- dynamic moduli --- railway application --- recycled material --- recycling --- sanitary ceramics --- concrete --- recycling aggregate --- asphalt mixture --- basalt fiber --- response surface methodology --- design optimization --- fluorescence spectrum --- bitumen --- ageing --- parametrization --- “blue-shift” --- asphalt --- asphalt mortar --- healing agents --- crack healing --- healing model --- ultra-thin wearing course --- self-healing --- induction heating --- steel fiber --- steel slag --- rankinite --- carbonation --- waste concrete --- CO2 --- aged bitumen --- rejuvenator --- solubilizer --- colloidal structure --- micro-morphology --- granite aggregate --- desulphurization gypsum residues --- rubber modified asphalt --- asphalt mixture --- pavement performance --- limestone aggregates --- emulsified asphalt --- demulsification speed --- surface energy --- specific surface area --- artificially aged asphalt mixture --- rejuvenator --- durability --- dynamic characteristics --- overlay tester --- energy-based approach --- dissipated strain energy --- plateau value of dissipated strain energy ratio --- fatigue life --- three-point bending fatigue test --- amorphous silica --- crystallization sensitivity --- water-leaching pretreatment --- rice husk ash --- cement --- crumb rubber --- anti-rutting agent --- flexibility --- field evaluation --- asphalt mixes --- aggregate characteristics --- simplex lattice design --- viscoelastic properties --- asphalt combustion --- flame retardant --- aluminum hydroxide --- layered double hydroxide --- asphalt mixture --- viscoelastic properties --- creep --- relaxation --- aggregates --- morphology --- crumb rubber powder --- SBS/CRP-modified bitumen --- aging processes --- temperature sensitivity characteristics --- diatomite --- basalt fiber --- asphalt mixture --- low-temperature --- damage constitutive model --- graphene --- nitrogen and phosphorus removal --- MDA --- SOD --- sequencing batch Chlorella reactor --- SEM --- thermal–mechanical properties --- bio-oil --- regeneration --- aged asphalt --- molecular dynamic simulation --- viscoelasticity --- nanomaterial --- hydrophobic nanosilica --- hydrophilic nanosilica --- laboratory evaluation --- diatomite --- basalt fiber --- compound modify --- asphalt mixture --- asphalt mixture --- basalt fiber --- freeze-thaw cycle --- damage characteristics --- high-modulus asphalt mixture (HMAM) --- dynamic tests --- viscoelasticity --- dynamic responses --- resistance to deformations --- tensile strains --- tensile stresses --- sensitivity analysis --- hot mix asphalt containing recycled concrete aggregate --- contact angle --- adhesion energy --- water stability --- fatigue performance --- self-compacting concrete (SCC) --- rheology --- workability --- pozzolanic reaction --- microstructure --- Ultra-High Performance Concrete (UHPC) --- long-term drying shrinkage --- hydration characteristic --- porous pumice --- optimization --- engineered cementitious composites (ECC) --- polyvinyl alcohol --- fiber modification --- mechanical behavior --- self-healing --- asphalt --- rejuvenation --- calcium alginate capsules --- asphalt-aggregate adhesion --- plant ash lixivium --- stripping test --- contact angle --- interfacial transition zone --- SBS-modified bitumen --- rejuvenating systems --- physical properties --- viscous-elastic temperature --- rutting factor --- vibration noise consumption --- cold recycled asphalt mixture --- reclaimed asphalt pavement --- mastic --- rheological properties --- emulsified asphalt --- cement --- construction materials --- fatigue life --- ageing resistance --- modified asphalt materials --- rejuvenator --- self-healing asphalt --- recycling --- cold recycled asphalt mixture --- ultra-high performance concrete

Environment-Friendly Construction Materials

Authors: --- --- ---
ISBN: 9783039210169 9783039210176 Year: Pages: 270 DOI: 10.3390/books978-3-03921-017-6 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-06-26 08:44:06
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Abstract

Construction materials are the most widely used materials for civil infrastructure in our daily lives. However, from an environmental point of view, they consume a huge amount of natural resources and generate the majority of greenhouse gasses. Therefore, many new and novel technologies for designing environmentally friendly construction materials have been developed recently. This Special Issue, “Environment-Friendly Construction Materials”, has been proposed and organized as a means to present recent developments in the field of construction materials. It covers a wide range of selected topics on construction materials.

Keywords

Ca-alginate microcapsules --- microfluidic --- self-healing --- bitumen --- mineral-asphalt mixtures --- aggregate from sanitary ceramic wastes --- environmentally friendly construction materials --- diatomite --- styrene–butadiene–styrene (SBS) modified bitumen --- diatomite-modified asphalt mixture --- road engineering --- fatigue life --- three-point bending fatigue test --- asphalt mixture --- plateau value of permanent deformation ratio --- damage evolution --- fatigue equation --- ultraviolet radiation --- bitumen --- aging depth --- transmittance --- permeation --- expanded graphite --- polyethylene glycol --- phase change materials --- titanate coupling agent --- molecular bridge --- building envelopes --- thermal property --- building energy conservation --- reclaimed asphalt pavement --- recycling --- epoxidized soybean oil --- rejuvenator --- diffusing --- asphalt pavement --- fatigue property --- pavement failure --- long-term field service --- asphalt mixture --- microwave heating --- induction heating --- effective heating depth --- induced healing --- initial self-healing temperature --- asphalt mastic --- flow behavior index --- steel slag --- limestone --- aggregate morphology --- aggregate image measurement system --- micro-surfacing --- skid-resistance --- surface texture --- asphalt --- water solute exposure --- aqueous solute compositions --- chemical evolutions --- rheological properties --- polyacrylic acid --- fluidity --- rheology --- adsorption --- combination --- cement emulsified asphalt mixture --- fatigue performance --- thickness combinations --- X-ray computed tomography --- artificial neural network --- crumb rubber --- high-strength concrete --- damping --- dynamic moduli --- railway application --- recycled material --- recycling --- sanitary ceramics --- concrete --- recycling aggregate --- asphalt mixture --- basalt fiber --- response surface methodology --- design optimization --- fluorescence spectrum --- bitumen --- ageing --- parametrization --- “blue-shift” --- asphalt --- asphalt mortar --- healing agents --- crack healing --- healing model --- ultra-thin wearing course --- self-healing --- induction heating --- steel fiber --- steel slag --- rankinite --- carbonation --- waste concrete --- CO2 --- aged bitumen --- rejuvenator --- solubilizer --- colloidal structure --- micro-morphology --- granite aggregate --- desulphurization gypsum residues --- rubber modified asphalt --- asphalt mixture --- pavement performance --- limestone aggregates --- emulsified asphalt --- demulsification speed --- surface energy --- specific surface area --- artificially aged asphalt mixture --- rejuvenator --- durability --- dynamic characteristics --- overlay tester --- energy-based approach --- dissipated strain energy --- plateau value of dissipated strain energy ratio --- fatigue life --- three-point bending fatigue test --- amorphous silica --- crystallization sensitivity --- water-leaching pretreatment --- rice husk ash --- cement --- crumb rubber --- anti-rutting agent --- flexibility --- field evaluation --- asphalt mixes --- aggregate characteristics --- simplex lattice design --- viscoelastic properties --- asphalt combustion --- flame retardant --- aluminum hydroxide --- layered double hydroxide --- asphalt mixture --- viscoelastic properties --- creep --- relaxation --- aggregates --- morphology --- crumb rubber powder --- SBS/CRP-modified bitumen --- aging processes --- temperature sensitivity characteristics --- diatomite --- basalt fiber --- asphalt mixture --- low-temperature --- damage constitutive model --- graphene --- nitrogen and phosphorus removal --- MDA --- SOD --- sequencing batch Chlorella reactor --- SEM --- thermal–mechanical properties --- bio-oil --- regeneration --- aged asphalt --- molecular dynamic simulation --- viscoelasticity --- nanomaterial --- hydrophobic nanosilica --- hydrophilic nanosilica --- laboratory evaluation --- diatomite --- basalt fiber --- compound modify --- asphalt mixture --- asphalt mixture --- basalt fiber --- freeze-thaw cycle --- damage characteristics --- high-modulus asphalt mixture (HMAM) --- dynamic tests --- viscoelasticity --- dynamic responses --- resistance to deformations --- tensile strains --- tensile stresses --- sensitivity analysis --- hot mix asphalt containing recycled concrete aggregate --- contact angle --- adhesion energy --- water stability --- fatigue performance --- self-compacting concrete (SCC) --- rheology --- workability --- pozzolanic reaction --- microstructure --- Ultra-High Performance Concrete (UHPC) --- long-term drying shrinkage --- hydration characteristic --- porous pumice --- optimization --- engineered cementitious composites (ECC) --- polyvinyl alcohol --- fiber modification --- mechanical behavior --- self-healing --- asphalt --- rejuvenation --- calcium alginate capsules --- asphalt-aggregate adhesion --- plant ash lixivium --- stripping test --- contact angle --- interfacial transition zone --- SBS-modified bitumen --- rejuvenating systems --- physical properties --- viscous-elastic temperature --- rutting factor --- vibration noise consumption --- cold recycled asphalt mixture --- reclaimed asphalt pavement --- mastic --- rheological properties --- emulsified asphalt --- cement --- construction materials --- fatigue life --- ageing resistance --- modified asphalt materials --- rejuvenator --- self-healing asphalt --- recycling --- cold recycled asphalt mixture --- ultra-high performance concrete

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