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Advanced Flame Retardant Materials

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ISBN: 9783039283507 9783039283514 Year: Pages: 190 DOI: 10.3390/books978-3-03928-351-4 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Physics (General) --- Science (General)
Added to DOAB on : 2020-04-07 23:07:09
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Abstract

Recent disasters caused by the spread of fire in buildings and in transportations remind us of the importance of fire protection. Using flame-retardant materials is one important element of the firefighting strategy, which aims to prevent fire development and propagation. These materials are used in different applications, such as in textiles, coatings, foams, furniture, and cables. The development of more efficient and environmentally friendly flame-retardant additives is an active multidisciplinary approach that has attracted a great deal of interest. Studies have aimed at the development of new, sustainable, and flame-retardant additives/materials, providing high performance and low toxicity. Also studied were their properties during ageing and recycling, as well as modeling physical and chemical processes occuring before ignition and during their combustion. The development of sustainable flame retardants and understanding their modes of action provide a strong link between these topics and cover many fields from organic chemistry, materials engineering, and toxicology, to physics and mathematics.

Polymeric Foams

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ISBN: 9783039216321 9783039216338 Year: Pages: 322 DOI: 10.3390/books978-3-03921-633-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Chemical Engineering
Added to DOAB on : 2019-12-09 11:49:16
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Advances in nanotechnology have boosted the development of more efficient materials, with emerging sectors (electronics, energy, aerospace, etc.) demanding novel materials to fulfill the complex technical requirements of their products. This is the case of polymeric foams, which may display good structural properties alongside functional characteristics through a complex composition and (micro)structure in which a gas phase is combined with rigid ones, mainly based on nanoparticles, dispersed throughout the polymer matrix. In recent years, there has been an important impulse in the development of nanocomposite foams, extending the concept of nanocomposites to the field of cellular materials. This, alongside developments in new advanced foaming technologies which have allowed the generation of foams with micro, sub-micro, and even nanocellular structures, has extended the applications of more traditional foams in terms of weight reduction, damping, and thermal and/or acoustic insulation to novel possibilities, such as electromagnetic interference (EMI) shielding. This Special Issue, which consists of a total of 22 articles, including one review article written by research groups of experts in the field, considers recent research on novel polymer-based foams in all their aspects: design, composition, processing and fabrication, microstructure, characterization and analysis, applications and service behavior, recycling and reuse, etc.

Keywords

grey relational analysis --- multi-objective particle swarm optimization --- acoustic performances --- Ethylene Propylene Diene Monomer --- polyurethane foam composites --- DOPO --- itaconic acid --- ethyl cellulose --- phenolic foams --- composites --- adjacent façade --- PUR --- energy conservation --- heat transfer --- burning characteristic --- semi-rigid polyurethane foams --- aluminum microfibers --- quasi-static compression tests --- mechanical properties --- energy absorption capability --- foams --- polyamide --- crystalline --- thermal conductivity --- mechanical property --- functional --- biomaterials --- composites --- EMI --- cellulose foam --- polypropylene --- foaming quality --- impact property --- intrinsic toughness --- flame-retardant ABS microcellular foams --- phosphorus flame retardants --- MuCell® injection-molding foaming --- graphene oxide --- rigid polyurethane foam --- thermogravimetric analysis --- activation energies --- extrusion foaming --- super critical CO2 --- lignin --- sound absorption coefficient --- mechanical property --- Pluronic --- surfactants --- foams --- SANS --- multilayers --- epoxy composite foam adhesive --- core–shell rubber --- impact wedge–peel test --- automobile structural adhesives --- flame retardancy --- foams --- phosphorus --- ternary synergistic effect --- polypropylene --- fluoelastomer --- scCO2 foaming --- heterogeneous nucleation --- polypropylene --- cellulose nanofiber --- foam injection molding --- mechanical properties --- polystyrene foams --- 1,3,5-benzene-trisamides --- cell nucleation --- foam extrusion --- foam morphology --- supramolecular additives --- thermal insulation --- compression properties --- piezoelectric --- functional foam --- piezocomposite --- PZT --- expandable microspheres --- permittivity --- polyetherimide foams --- graphene --- multifunctional foams --- ultrasonication --- scCO2 --- electrical conductivity --- polymer waste --- polyurethane foam --- leaching test --- microstructure --- absorbent PMI foam --- metallic tube --- electromagnetic wave absorption --- mechanical properties --- failure mechanism --- polymers --- foams --- shock compression --- equation of state --- epoxy --- foams --- expandable microspheres --- graphene --- nanotubes --- conductivity --- syntactic foams --- n/a

POSS-Based Polymers

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ISBN: 9783039219940 9783039219957 Year: Pages: 310 DOI: 10.3390/books978-3-03921-995-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-01-07 09:08:26
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Abstract

The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.

Keywords

direct synthesis --- grafting synthesis --- mercapto-modified --- bridged silsesquioxane --- polyhedral oligomeric silsesquioxanes --- POSS --- composites --- thermal stability --- fluorescent sensors --- nitroaromatic explosives --- polyhedral oligomeric silsesquioxane-based ionic liquids --- self-assembly behaviors --- thiol-ene ‘click’ reaction --- siloxane-silsesquioxane resins --- polypropylene --- thermogravimetry --- cone calorimeter tests --- flame-retardant mechanism --- POSS --- filler --- low refractive material --- thermal stability --- fluoropolymer --- polyhedral oligomeric silsesquioxane (POSS) --- double-decker-shaped silsesquioxane (DDSQ) --- polyimide --- thermal stability --- dielectric constant --- poly(?-caprolactone) nanocomposite --- POSS nanoparticles --- dispersion --- morphology --- thermal properties --- mechanical properties --- surface properties --- phthalonitrile polymers --- phthalonitrile-polyhedral oligomeric silsesquioxane copolymers --- cyanate ester --- blends --- thermal properties --- POSS-based copolymer --- graphene oxide --- flame retardant --- epoxy resin --- giant surfactant --- thiol–ene “click” reaction --- polyhedral oligomeric silsesquioxane (POSS) --- poly(?-caprolactone) --- aqueous self-assembly --- POSS --- ridgid polyurethane foams --- mechanical properties --- cellular structure --- bi-functional POSS --- hydrophobic modification --- thermoplastic polyurethane --- mechanical performance --- silsesquioxanes --- optoelectronics --- OLEDs --- Monomethacryloxy POSS --- lauryl methacrylate --- polymerization kinetics --- anchor effect --- octa-ammonium POSS --- sodium alginate --- hydrogels --- temperature responsiveness --- Octavinyl-POSS --- organic-inorganic crosslinking --- Si@C anode --- lithium ion battery --- mechanism analysis --- monodisperse --- nanocomposites --- damping --- POSS --- liquefied --- benzoxazine --- POSS --- organic-inorganic hybrids --- epoxy resin --- thermal properties --- flame retardancy --- n/a

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MDPI - Multidisciplinary Digital Publishing Institute (3)


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CC by-nc-nd (3)


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english (3)


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2020 (1)

2019 (2)