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Analysis of Hydrogen Bonds in Crystals

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ISBN: 9783038422457 9783038422464 Year: Pages: XIV, 308 DOI: 10.3390/books978-3-03842-246-4 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General)
Added to DOAB on : 2016-08-29 12:35:45
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There is no doubt that the hydrogen bond is one of the most-often analyzed interactions, and there is also no doubt that experimental studies, especially those based on the determination of crystal structures are very important since they deliver valuable information on the nature of this interaction, on different types of the hydrogen bonds, and also on reactions where a hydrogen bond may be treated as the preliminary step.Since the role of the analysis of crystal structures for investigations concerning hydrogen-bonded systems is valuable, the Editorial Board of Crystals, thus, decided to devote a Special Issue of the journal to the analysis of hydrogen bonds in crystals.

Polyhedral Structures, Symmetry, and Applications

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ISBN: 9783038426899 9783038426882 Year: Pages: 322 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Mathematics
Added to DOAB on : 2018-02-08 13:24:15
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Symmetry is an intriguing phenomenon manifesting itself in art, nature, and the mind. This Special Issue book features 19 articles about discrete geometric and combinatorial polyhedral structures, with symmetry as the unifying theme. These articles present an attractive mix of topics and have appeared in two related Special Issues of Symmetry, on "Polyhedra" in 2012/2013 and on "Polyhedral Structures" in 2016/2017. Specific topic areas covered include polyhedra, tilings, and crystallography; abstract polyhedra, maps on surfaces, and graphs; and polyhedral structures, arts, and architectural design.

High-Pressure Studies of Crystalline Materials

ISBN: 9783038971313 9783038971320 Year: Pages: 330 DOI: 10.3390/books978-3-03897-132-0 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General) --- Mathematics --- Environmental Sciences
Added to DOAB on : 2018-09-20 10:13:12
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[This book is a printed edition of the Special Issue of Crystals: High-Pressure Studies of Crystalline Materials. It also includes additional articles published in Crystals and related to the topic of the Special Issue, which have been selected based upon their relevance and scientific quality.]

Physiology and Pathophysiology of the Extracellular Calcium-Sensing Receptor

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Book Series: Frontiers Research Topics ISSN: 16648714 ISBN: 9782889455126 Year: Pages: 189 DOI: 10.3389/978-2-88945-512-6 Language: English
Publisher: Frontiers Media SA
Subject: Science (General) --- Physiology
Added to DOAB on : 2019-01-23 14:53:42
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Calcium is vital for human physiology; it mediates multiple signaling cascades, critical for cell survival, differentiation, or death both as first and as second messenger. The role of calcium as first messenger is mediated by the G-protein coupled receptor, the extracellular calcium-sensing receptor (CaSR). The CaSR is a multifaceted molecule that senses changes in the concentration of a wide variety of environmental factors including di- and trivalent cations, amino acids, polyamines, and pH. In calcitropic tissues with obvious roles in calcium homeostasis such as parathyroid, kidney, and bone it regulates circulating calcium concentrations. The germline mutations of the CaSR cause parathyroid disorders demonstrating the importance of the CaSR for the maintenance of serum calcium homeostasis. The CaSR has an important role also in a range of non-calcitropic tissues, such as the intestine, lungs, central and peripheral nervous system, breast, skin and reproductive system, where it regulates molecular and cellular processes such as gene expression, proliferation, differentiation and apoptosis; as well as regulating hormone secretion and lactation.This Research Topic is an overview of the CaSR and its molecular signaling properties together with the various organ systems where it plays an important role. The articles highlight the current knowledge regarding many aspects of the calcitropic and non-calcitropic physiology and pathophysiology of the CaSR.

Compounds with Polar Metallic Bonding

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ISBN: 9783039210701 / 9783039210718 Year: Pages: 154 DOI: 10.3390/books978-3-03921-071-8 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General) --- Inorganic Chemistry
Added to DOAB on : 2019-08-28 11:21:27
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The Special Edition 'Compounds with Polar Metallic Bonding' is a collection of eight original research reports presenting a broad variety of chemical systems, analytical methods, preparative pathways and theoretical descriptions of bonding situations, with the common aim of understanding the complex interplay of conduction electrons in intermetallic compounds that possess different types of dipoles. Coulombic dipoles introduced by electronegativity differences, electric or magnetic dipoles, polarity induced by symmetry reduction—all the possible facets of the term 'polarity'—can be observed in polar intermetallic phases and have their own and, in most cases, unique consequences on the physical and chemical behaviour. Elucidation of the structure–property relationships in compounds with polar metallic bonding is a modern and growing scientific field which combines solid state physics, preparative chemistry, metallurgy, modern analytic methods, crystallography, theoretical calculations of the electronic state and many more disciplines.

Crystal Structures of Compounds Containing Ions Selenite

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ISBN: 9783038975175 / 9783038975182 Year: Pages: 106 DOI: 10.3390/books978-3-03897-518-2 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General)
Added to DOAB on : 2019-01-17 10:59:27
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The chemistry of materials containing Se oxyanions in the +4 oxidation state, such as selenite, hydrogenselenite, and oxoselenate, are of increasing interest in the research community for several reasons. First, the lone pair on the selenium atom can behave as structure-directing agent towards the formation of materials characterized by the presence of hollows or channels in their intimate structures, moreover, the weakly coordinative capability of the Se(IV) electron lone pairs could give rise to interesting supramolecular interactions, and finally, it is known that the incorporation of selenite anions can lead to non-centrosymmetric structures and, consequently, to materials displaying remarkable physicochemical properties.The most important feature is that the full comprehension of the properties of this type of materials cannot be exhaustively understood unless the complete solid state crystal structure is available. In this Special Issue, entitled “Crystal Structures of Compounds Containing Ions Selenite”, a series of new selenite-containing compounds synthesized by different methodologies and fully caracterized in the solid state is reported. Moreover the fundamental role of detailed structural analysis in understanding the interactions in the solid state that are responsible for the peculiar chemical–physical properties of such materials is discussed.

New Mineral Species and Their Crystal Structures

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ISBN: 9783038976882 Year: Pages: 204 DOI: 10.3390/books978-3-03897-689-9 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-04-05 11:07:22
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One last comment concerns the fundamental contributions of Fourier analysis to quantum physics: Quantum mechanics and quantum field theory.

Keywords

ariegilatite --- nabimusaite group --- new mineral --- crystal structure --- intercalated hexagonal antiperovskite --- CO3-group --- Raman --- pyrometamorphic rocks --- Hatrurim Complex --- tiberiobardiite --- chalcophyllite group --- copper --- silicate --- sulfate --- Cretaio --- Tuscany --- Italy --- oyonite --- lillianite homologous series --- sulfosalt --- copper --- antimony --- arsenic --- Oyon district --- Lima department --- Peru --- fiemmeite --- new oxalate mineral --- Val di Fiemme --- Trentino --- Italy --- sharyginite --- new mineral --- crystal structure --- Raman spectroscopy --- Bellerberg volcano --- Germany --- kurchatovite --- clinokurchatovite --- crystal structure --- borate --- polymorphism --- polytypism --- structural complexity --- structural combinatorics --- configurational entropy --- least-action principle --- barioferrite --- crystal structure --- single-crystal investigation --- Raman --- Hatrurim Complex --- Rusinovite --- Raman spectroscopy --- pyrometamorphism --- stacking faults --- Shadil-Khokh volcano --- Bellerberg volcano --- aurihydrargyrumite --- Au6Hg5 phase --- gold --- placer --- self-electrorefining --- Ehime --- Japan --- cerromojonite --- selenium --- copper --- lead --- mercury --- bismuth --- sou?ekite --- bournonite group --- El Dragón --- Bolivia --- nöggerathite-(Ce) --- new mineral --- zirconolite --- laachite --- sanidinite --- crystal structure --- alkaline volcanic rock --- Laacher See --- Eifel --- parafiniukite --- apatite supergroup --- hedyphane group --- manganese --- calcium --- phosphorus --- Szklary pegmatite --- Lower Silesia --- Poland --- thermaerogenite --- cuprospinel --- gahnite --- magnesioferrite --- CuAl2O4 --- CuFe2O4 --- copper oxide --- new mineral --- spinel supergroup --- fumarole sublimate --- Tolbachik volcano --- Kamchatka --- verneite --- new mineral --- crystal structure --- Hekla --- Vesuvius --- Eldfell --- aluminofluoride

Crystal Chemistry of Zinc, Cadmium and Mercury

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ISBN: 9783038976523 Year: Pages: 156 DOI: 10.3390/books978-3-03897-653-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Organic Chemistry --- Chemistry (General) --- Science (General)
Added to DOAB on : 2019-04-05 10:34:31
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This book is a printed edition of the Special Issue Crystal Chemistry of Zinc, Cadmium and Mercury that was published in Crystals

Arctic Mineral Resources. Science and Technology

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ISBN: 9783038978244 9783038978251 Year: Pages: 432 DOI: 10.3390/books978-3-03897-825-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General)
Added to DOAB on : 2019-04-25 16:37:17
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The Arctic zone of the Earth is a major source of mineral and other natural resources for the future development of science and technology. It contains a large supply of strategic mineral deposits, including rare earths, copper, phosphorus, niobium, platinum-group elements, and other critical metals. The continued melting of the sea ice due to climate change makes these resources more accessible than ever before. However, the mineral exploration in the Arctic has always been a challenge due to the climatic restrictions, remote location, and vulnerability of Arctic ecosystems. This book covers a broad range of topics related to the problem of Arctic mineral resources, including geological, geochemical, and mineralogical aspects of their occurrence and formation; chemical technologies; and environmental and economic problems related to mineral exploration. The contributions can be tentatively classified into four major types: geodynamics and metallogeny, mineralogy and petrology, mineralogy and crystallography, and mining and chemical technologies associated with the exploration of mineral deposits and the use of raw materials for manufacturing new products. The book can be of interest for all those interested in Arctic issues and especially in Arctic mineral resources and associated problems of mineralogy, geology, geochemistry, and technology.

Keywords

forsterite --- typochemistry --- crystal structure --- Kovdor phoscorite–carbonatite complex --- pyrochlore supergroup minerals --- typochemistry --- crystal structure --- Kovdor phoscorite-carbonatite complex --- pyrrhotite --- chalcopyrite --- pentlandite --- cobaltpentlandite --- typochemistry --- crystal structure --- Kovdor phoscorite-carbonatite complex --- shkatulkalite --- titanosilicate --- crystal structure --- Kola Peninsula --- Lovozero alkaline massif --- transformation mineral species --- vuonnemite --- titanium --- niobium --- heap leaching --- bacterial leaching --- cryomineralogenesis --- low-grade copper-nickel ore --- raw materials --- apatite-nepheline-titanite ore --- sulfuric-acidic decomposition --- titanyl sulfate --- hydrothermal synthesis --- ivanyukite --- batievaite-(Y) --- hainite-(Y) --- titanosilicate --- rinkite group minerals --- Kola Peninsula --- Sakharjok massif --- Keivy alkaline province --- transformation mineral species --- vanadium mineralization --- mineralogy --- Paleoproterozoic --- Kola region --- Arctic zone --- Fennoscandian Shield --- zircon --- macrocrysts --- kimberlite --- trace elements --- geochronology --- cathodoluminescence --- Ti-in-zircon geothermometry --- antigorite --- ore dressing tailings --- mechanical activation --- alkali-activated binder --- Yenisei-Khatanga basin --- Siberian craton --- Arctic --- oil --- gas --- petroleum potential --- geodynamics --- apatite --- Khibiny --- apatite-nepheline deposit --- phase diagram apatite-nepheline-diopside --- silicocarbonatite --- melteigite --- calcite --- nepheline --- zeolite group minerals --- garnet --- crystal fractionation --- Breivikbotn --- Northern Norway --- saponite-containing waters --- diamond processing plants --- cryogenic treatment --- electrochemical separation --- saponite product applications --- U mineralization --- hydrothermal deposits --- U-Pb --- Rb-Sr --- Kola region --- evolution of the composition --- basic rocks --- Precambrian --- search of trend differences --- geodynamic evolution --- metallogeny --- beryllium minerals --- chemical composition --- mineral data --- alkaline rocks --- granite --- pegmatites --- hydrothermal veins --- Kola Peninsula --- Plume --- LIP --- PGE --- Palaeoproterozoic --- mafic intrusion --- U-Pb --- isotopes --- PGE --- South Reef --- West-Pana intrusion --- Fedorova-Pana Complex --- zircon dating --- U-Pb --- Khibiny promising structures --- conductive layers --- MHD-source “Khibiny”, Pechenga structure --- Kola Peninsula --- greenstone belt --- gold --- Kola Peninsula --- Northern Karelia --- rock alteration --- n/a

Molecular Magnets

Authors: ---
ISBN: 9783038977100 Year: Pages: 166 DOI: 10.3390/books978-3-03897-711-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General)
Added to DOAB on : 2019-03-21 14:08:22
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Molecular magnets show many properties not met in conventional metallic magnetic materials, i.e. low density, transparency to electromagnetic radiation, sensitivity to external stimuli such as light, pressure, temperature, chemical modification or magnetic/electric fields, and others. They can serve as “functional” materials in sensors of different types or be applied in high-density magnetic storage or nanoscale devices. Research into molecule-based materials became more intense at the end of the 20th century and is now an important branch of modern science. The articles in this Special Issue, written by physicists and chemists, reflect the current work on molecular magnets being carried out in several research centers. Theoretical papers in the issue concern the influence of spin anisotropy in the low dimensional lattice of the resulting type of magnet, as well as thermodynamics and magnetic excitations in spin trimers. The impact of external pressure on structural and magnetic properties and its underlying mechanisms is described using the example of Prussian blue analogue data. The other functionality discussed is the magnetocaloric effect, investigated in coordination polymers and high spin clusters. In this issue, new molecular magnets are presented: (i) ferromagnetic high-spin [Mn6] single-molecule magnets, (ii) solvatomagnetic compounds changing their structure and magnetism dependent on water content, and (iii) a family of purely organic magnetic materials. Finally, an advanced calorimetric study of anisotropy in magnetic molecular superconductors is reviewed.

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