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On the diverse bonding situations in nanostructures : an ab initio computational study

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ISBN: 9783866444508 Year: Pages: VIII, 131 p. DOI: 10.5445/KSP/1000013975 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Chemistry (General)
Added to DOAB on : 2019-07-30 20:01:58
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This computational study investigates diverse bonding situations in nanostructures (carbon nanotubes, fullerenes, metal compounds) spanning a broad range of energies. Weak, dispersive interactions and covalent metal-ligand and metal-metal bonding are examined. The results of efficient density functional calculations are compared to those of correlated wavefunction calculations on model systems. This rigorous validation is crucial in evaluating the balance between computational cost and accuracy.

STM Characterization of Phenylene-Ethynylene Oligomers on Au(111) and their Integration into Carbon Nanotube Nanogaps

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Book Series: Experimental Condensed Matter Physics / Karlsruher Institut für Technologie, Physikalisches Institut ISSN: 21919925 ISBN: 9783731502357 Year: Volume: 12 Pages: 125 p. DOI: 10.5445/KSP/1000041811 Language: ENGLISH
Publisher: KIT Scientific Publishing
Subject: Physics (General)
Added to DOAB on : 2019-07-30 20:01:58
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Molecular electronics requires both profound knowledge of a molecule's structure and functionality on a surface and controlled positioning between electrodes with nanometer-sized gaps. In the first part of this work, a detailed scanning tunneling microscope study of two variants of oligo(phenylene ethynylene) molecules is presented. In the second part, methods of fabricating carbon nanotube nanogap electrodes as direct contacts to these molecules are explored.

Multi-Walled Carbon Nanotubes

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ISBN: 9783039212293 9783039212309 Year: Pages: 184 DOI: 10.3390/books978-3-03921-230-9 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Chemical Engineering
Added to DOAB on : 2019-08-28 11:21:27
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Since their discovery, multi-walled carbon nanotubes (MWCNTs) have received tremendous attention due to their unique electrical, optical, physical, chemical, and mechanical properties. Remarkable advances have been made in the synthesis, purification, structural characterization, functionalization, and application of MWCNTs. Their particular characteristics make them well suited for a plethora of applications in a number of fields, namely nanoelectronics, nanofluids, energy management, (electro)catalysis, materials science, construction of (bio)sensors based on different detection schemes, multifunctional nanoprobes for biomedical imaging, and sorbents for sample preparation or removal of contaminants from wastewater. They are also useful as anti-bacterial agents, drug delivery nanocarriers, etc. The current relevant application areas are countless. This Special Issue presents original research and review articles that address advances, trends, challenges, and future perspectives regarding synthetic routes, structural features, properties, behaviors, and industrial or scientific applications of MWCNTs in established and emerging areas.

Keywords

water based nanofluid --- carbon-nanotubes --- boundary layer --- heat generation --- thermal radiation --- curved stretching sheet --- numerical solution --- Single-Walled Carbon Nanotube (SWCNT) --- Multi-Walled Carbon Nanotube (MWCNT) --- MHD --- Casson model --- stretching sheet --- non-linear thermal radiation --- HAM --- zeolitic imidazolate framework --- multi-walled carbon nanotubes --- magnetic solid phase extraction --- organochlorine pesticides --- agricultural irrigation water --- Pd-CNT nanohybrids --- functionalized CNTs --- polarity --- semi-homogeneous catalysis --- heck reaction --- nanomaterials --- multi-walled carbon nanotubes --- synthesis methods --- electrochemical properties --- electrochemical sensors --- electroanalysis --- sensing applications --- multiwalled carbon nanotubes --- gold(I) --- gold(III) --- adsorption --- elution --- gold nanoparticles --- adsorption --- multi-walled carbon nanotubes --- nonylphenol --- kinetics --- multi-walled carbon nanotubes --- graphene oxide --- cerium oxide --- lubricating oil additives --- multi-wall carbon nanotube (MWCNT) --- azide-alkyne click chemistry --- RAFT polymerization --- PMMA --- carbon nanotubes --- composites --- radar absorbing materials --- complex permittivity --- chloride diffusion --- cement mortars --- carbon nanotubes --- mechanical properties --- electrical properties --- hydrophobic drugs --- drug delivery --- functionalized carbon nanotubes --- dissolution rate --- nanomedicine --- polymeric composites --- silicone rubber --- Ionic liquid --- carbon materials --- structural --- EMI shielding --- n/a

Nanomaterials for Environmental Purification and Energy Conversion

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ISBN: 9783039218141 9783039218158 Year: Pages: 264 DOI: 10.3390/books978-3-03921-815-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering --- Environmental Engineering
Added to DOAB on : 2020-04-07 23:07:08
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The Special Issue, “Nanomaterials for Environmental Purification and Energy Conversion”, describes the significant and increasing role of nanomaterials in catalysis. It is believed that the most important factor for future human development could be to use nanomaterials (nanotechnology) to solve such critical issues facing humanity such as environment, water and energy. It should be also pointed out that properties of nanomaterials differ substantially from that of bulk materials of the same composition, resulting in high reactivity. Therefore, it creates new perspectives for the catalytic processes in the broad sense. This issue was mainly dedicated as a platform for the contributions from The Symposium on Nanomaterials for Environmental Purification and Energy Conversion (SNEPEC), which was held in Sapporo, Japan in winter 2018. Accordingly, this book compiles the current state-of-the-art of research in the area of novel photocatalysts and highlights current research directions in the fields of advanced oxidation technologies, material science and nanotechnology. Written by leading experts in the field of photochemistry and chemical engineering, a collection of 17 papers, including 16 research papers and one review, covers a broad range of topics focusing on the exceptional role of catalytic nanomaterials in solving environmental and energy problems of modern societies. The majority of papers present the importance of photocatalytic nanomaterials, especially for degradation of organic pollutants and inactivation of microorganisms, but there is also a strong representation of conventional catalysis, based on nanomaterials for important processes such as catalytic hydrogen production and organic synthesis.

Keywords

TiOF2 --- NaOH-modified TiOF2 --- network shape --- photocatalysis --- RhB --- chemical looping reforming of methane --- yttrium promoted oxygen carrier --- SBA-16 --- hydrogen production --- conductive cotton filter --- carbon nanotubes --- low-cost --- water purification --- gravity feed --- alcohols --- salicylic acid --- multiwalled carbon nanotubes --- synthesis gas --- titanium dioxide --- graphene --- photocatalysis --- visible light --- dyes --- Cu nanoparticles --- Cu/FTO nanocomposites --- H2 evolution --- visible light --- transfer efficiency --- chemical looping --- oxygen carrier --- hydrogen production --- narrow pore size distribution --- Fe2O3 dispersion --- texture modification --- photocatalytic reduction --- TiO2 --- anatase --- CO2 --- flue gas --- adsorption --- magnetic ZnO --- methylene blue --- photodegradation --- rectorite --- dimethyl carbonate --- carbon dioxide --- ceria nanowires --- oxygen vacancy --- Pt-Au --- XAFS --- BCLA --- zinc chromite --- photocatalysis activity --- oxalate --- humic acid --- photocatalysis --- CO2 reduction --- anatase --- polydopamine --- sensitization --- heterogeneous photocatalysis --- TiO2/Cu2O nanotubes --- anodization --- nanomaterials fabrication --- removal of microbiological pollutants --- photocatalysis --- nanocomposites --- heterojunction --- Cu2O --- urea --- polytriazine --- Z-scheme --- ionic liquids --- ionic liquid-assisted solvothermal reaction --- reaction time --- titanium dioxide --- heterogeneous photocatalysis --- visible light --- C/TiO2 --- photocatalysis --- solar radiation --- disinfection --- immobilized catalyst --- n/a

Carbonates

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ISBN: 9783038977223 Year: Pages: 146 DOI: 10.3390/books978-3-03897-723-0 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Physics (General) --- Science (General)
Added to DOAB on : 2019-04-05 10:34:31
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This Special Issue is aimed at presenting the state of the art of the multidisciplinary science concerning all aspects of volcanic plumes, of relevance to the volcanology, climatology, atmospheric science, and remote sensing communities.

Carbon Based Electronic Devices

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ISBN: 9783039282326 9783039282333 Year: Pages: 258 DOI: 10.3390/books978-3-03928-233-3 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: General and Civil Engineering --- Technology (General)
Added to DOAB on : 2020-04-07 23:07:08
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For more than 50 years, silicon has dominated the electronics industry. However, this growth will come to an end, due to resources limitations. Thus, research developments need to focus to alternative materials, with higher performance and better functionality. Current research achievements have indicated that carbon is one of the promising candidates for its exploitation in the electronics industry. Whereas the physical properties of graphite and diamond have been investigated for many years, the potential for electronic applications of other allotropes of carbon (fullerenes, carbon nanotubes, carbon nanofibres, carbon films, carbon balls and beads, carbon fibers, etc), has only been appreciated relatively recently. Carbon-based materials offer a number of exciting possibilities for new applications of electronic devices, due to their unique thermal and electrical properties. However, the success of carbon-based electronics depends on the rapid progress of the fabrication, doping and manipulation techniques. In this Special Issue, we focus on both insights and advancements in carbon-based electronics. We will also cover various topics ranging from synthesis, functionalisation, and characterisation of carbon-based materials, for their use in electronic devices, including advanced manufacturing techniques, such as 3D printing, ink-jet printing, spray-gun technique, etc.

Keywords

ionization sensor array --- NOx --- carbon nanotube (CNT) --- selectivity --- non-self-sustaining discharge --- carbon nanotube --- field emitters --- electrical aging --- Joule heating --- electron emission --- photosensor --- reduced graphene oxide --- Ag nanoparticles --- solution process --- finite-difference time-domain --- carbon nanofibres (CNFs) --- active-screen plasma sputtering (ASPS) technology --- supercapacitors (SCs) --- silver (Ag) --- platinum (Pt) and palladium (Pd) nanoparticles --- transparent conducting electrode --- flexible electrode --- graphene --- optoelectronic device --- graphene --- Galinstan --- Liquid-Metal --- spray-on --- aerosol --- honey --- mobility --- contact resistance --- TLM --- I-V characteristics --- porous electrode --- pressure sensitivity --- self-powered sensors --- mechanical impact --- carbon nanofillers --- electrical conductivity --- piezoresistive behavior --- ReRAM --- carbon nanofibers --- spray-gun deposition --- carbon Inks --- rheology --- additive manufacturing --- graphene --- carbon nanotubes --- printing --- supercapacitors --- graphene oxide --- metal nanoparticles --- dodecylbenzene sulfonic acid (DBSA) doped polyaniline --- capacitance --- humidity sensor --- carbon-based materials --- carbon nanotubes --- graphene --- carbon black --- carbon fibers --- carbon soot --- biochar --- flexible electronics --- carbon nanotubes --- graphene --- carbon fibres --- functionalization --- supercapacitors --- sensors --- inkjet printer inks --- flexible wearable devices --- electronics --- carbon-based material --- carbon structure differentiation --- NEMS quality --- higher performances --- revised Raman characterization --- quantum electronic activation --- carbon phase transition --- n/a

Solid Catalysts for the Upgrading of Renewable Sources

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ISBN: 9783038975724 Year: Pages: 226 DOI: 10.3390/books978-3-03897-573-1 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General) --- Science (General)
Added to DOAB on : 2019-04-05 11:07:22
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The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies.

Food Packaging. Materials and Technologies

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ISBN: 9783038977667 9783038977674 Year: Pages: 216 DOI: 10.3390/books978-3-03897-767-4 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering --- Materials
Added to DOAB on : 2019-04-25 16:37:17
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Because of the increasing pressure on both food safety and packaging/food waste, the topic is important both for academics, applied research, industry and also for environment protection. Different materials, such as glass, metals, paper and paperboards, and non-degradable and degradable polymers, with versatile properties, are attractive for potential uses in food packaging. Food packaging is the largest area of application within the food sector. Only the nanotechnology-enabled products in the food sector account for ~50% of the market value, with and the annual growth rate is 11.65%. Technological developments are also of great interest. In the food sector, nanotechnology is involved in packaging materials with extremely high gas barriers, antimicrobial properties, and also in nanoencapsulants for the delivery of nutrients, flavors, or aromas, antimicrobial, and antioxidant compounds. Applications of materials, including nanomaterials in packaging and food safety, are in forms of: edible films, polymer nanocomposites, as high barrier packaging materials, nanocoatings, surface biocides, silver nanoparticles as potent antimicrobial agents, nutrition and neutraceuticals, active/bioactive packaging, intelligent packaging, nanosensors and nanomaterial-based assays for the detection of food relevant analytes (gasses, small organic molecules and food-borne pathogens) and bioplastics.

ECO-COMPASS

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ISBN: 9783038976905 9783038976912 Year: Pages: 219 DOI: 10.3390/books978-3-03897-691-2 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Media and communication --- Transportation
Added to DOAB on : 2019-08-28 11:21:28
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Today, mainly man-made materials, such as carbon and glass fibers, are used to produce composite parts in aviation. Renewable materials, such as natural fibers or bio-sourced resin systems, have not yet found their way into aviation. The project ECO-COMPASS aims to evaluate the potential applications of ecologically improved composite materials in the aviation sector in an international collaboration of Chinese and European partners. Natural fibers such as flax and ramie will be used for different types of reinforcements and sandwich cores. Furthermore, bio-based epoxy resins to substitute bisphenol-A based epoxy resins in secondary structures are under investigation. Adapted material protection technologies to reduce environmental influence and to improve fire resistance are needed to fulfil the demanding safety requirements in aviation. Modelling and simulation of chosen eco-composites aims for an optimized use of materials while a Life Cycle Assessment aims to prove the ecological advantages compared to synthetic state-of-the-art materials. This Special Issue provides selected papers from the project consortium partners.

Application and Behavior of Nanomaterials in Water Treatment

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ISBN: 9783039211715 9783039211722 Year: Pages: 174 DOI: 10.3390/books978-3-03921-172-2 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-12-09 11:49:15
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The book compiles scientific articles describing advances in nanomaterial synthesis and their application in water remediation. The publications treat diverse problems such as dye degradation, heavy metal ion, as well as radioactive element capture and sequestration. There are 10 original research articles and one review article. The latter proposes graphene/CNT and Prussian blue nanocomposites for radioactive 137-cesium extraction from aqueous media. All reports thoroughly characterize the nanomaterials post-synthesis and describe their catalytic, photocatalytic, or ion exchange activities in contaminated water. The dyes studied in the collection are azo dyes, i.e. methylene blue and orange, rhodamine B, phenolic dyes viz. bromophenol blue, and other dyes with sulfonyl groups. Extraction of radioactive elements, including cationic 137Cs+ and anionic 125I?, is also investigated. The omnipresence of ZnO nanoparticles in everyday products and their effects in wastewater are also evaluated. Layered double hydroxide are capable of capturing Ag ions, which then has a catalytic effect on dye degradation. The nanomaterials considered are varied, viz., graphene, CNT, Prussian blue, nanoporous carbon, layered double hydroxides, magnetite, ferrites, organic powders, polymer membranes, bacteria, and inorganic nanomaterials such as MnO and Ag. The book targets an interdisciplinary readership.

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