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This book is dedicated to highlighting some relevant advances in the field of thin films and coatings based on two-dimensional crystals and layered nanomaterials. Due to their layered structure, graphene and a variety of new 2D inorganic nanosystems, called “graphene analogues”, have all attracted tremendous interest due to their unprecedented properties/superior performance, and may find applications in many fields from electronics to biotechnology. These two-dimensional systems are ultrathin and, hence, tend to be flexible, also presenting distinctive and nearly intrinsic characteristics, including electronic, magnetic, optical, thermal conductivity, and superconducting properties. Furthermore, the combination of different structures and synergetic effects may open new and unprecedented perspectives, making these ideal advanced materials for multifunctional assembled systems. As far as the field of coatings is concerned, new layered nanostructures may offer unique and multifunctional properties, including gas barrier, lubricant, conductive, magnetic, photoactive, self-cleaning, and/or antimicrobial surfaces. This book contains new findings on the synthesis and perspectives of multifunctional films that are at the forefront of the science and coating technologies.
MoS2 nanosheets --- Pt nanoparticles --- counter electrode --- dye-sensitized solar cells --- graphene --- bubble transfer --- electrochemical delamination --- Cu film --- nondestructive --- reusability --- graphene/MoS2/Si heterostructure --- chemical vapor deposition --- energy conversion efficiency --- photoresponse --- electroless NiP alloy --- carbon nitride --- composites coating --- corrosion --- microhardness --- graphene --- epitaxial growth --- chemical vapor deposition --- plasma --- combustion --- PEMFC --- nanowire --- graphene --- PtPd --- 2D --- graphene --- free-standing films --- thermal conductivity --- thermal management --- chemical vapor transport deposition --- molybdenum disulfide --- monolayer --- water --- mechanism --- surface enhanced Raman spectroscopy --- two-dimensional materials --- plasmonic structure --- chemical vapor transport deposition --- tungsten disulfide --- monolayer --- photoluminescence --- microbial fuel cells --- stainless steel mesh electrode --- graphene --- graphene suspension --- air-cathode --- coatings --- 2D materials --- layered materials --- graphene --- reduced graphene oxide --- transition metal dichalcogenides --- WS2 --- MoS2 --- transition metal carbides --- transition metal nitrides --- transition metal carbonitrides --- silicene --- germanene --- stanene --- van der Waals heterostructures --- interfaces
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Metal–organic frameworks are among the most promising novel materials. The concept of MOFs was first introduced in 1990. They were actually initially used in catalysis, gas separation, membranes, electrochemical sensors. Later on, they were introduced as SPE sorbents for PAHs (Polycyclic Aromatic Hydrocarbons) in environmental water samples, then the range expanded to the field of analytical chemistry, both in chromatographic separation and sample preparation, with great success in, e.g., SPE and SPME (Solid Phase Mico-extraction). Since then, the number of analytical applications implementing MOFs as sorbents in sorptive sample preparation approaches is increasing. ?his is reinforced by the fact that, at least theoretically, an infinite number of structures can be designed and synthesized, thus making tuneability one of the most unique characteristics of MOF materials. Moreover, they have been designed in various shapes, such as columns, fibers, and films, so that they can meet more analytical challenges with improved analytical features.Their exceptional properties attracted the interest of analytical chemists who have taken advantage of the unique structures and properties and have already introduced them in several sample pretreatment techniques, such as solid phase extraction, dispersive SPE, magnetic solid phase extraction, solid phase microextraction, stir bar sorptive extraction, etc.
metal-organic framework --- chitosan beads --- adsorption --- Pb(II) --- metal-organic frameworks --- MOF --- sample preparation --- HPLC --- GC --- food samples --- metal–organic frameworks --- dispersive miniaturized solid-phase extraction --- mixed functionalization --- interactions MOF–analyte --- UiO-66 --- metal organic framework (MOF) --- adsorptive desulfurization of fuels --- thiophenic compounds --- dibenzothiophene (DBT) --- 4,6-dimethyldibenzothiophene (4,6-DMDBT) --- metal organic framework composites --- oxidized graphitic carbon nitride nanoparticles --- porosity --- structural heterogeneity --- MOFs --- metals --- extraction --- sample preparation --- microextraction --- spectrometry --- environmental samples --- food samples --- biological samples --- metal organic framework --- polymer nanocomposites --- drug delivery --- magnetic resonance imaging --- metal-organic frameworks --- MOFs --- fish --- extraction --- antibiotics --- antimicrobial agents --- metal ions --- metal-organic frameworks --- luminescence --- lanthanides --- color tuning --- doping --- temperature sensors --- metal-organic framework --- mixed-ligand --- pillared --- paddle-wheel --- non-catenated --- large-pore --- hydrogen-bonding --- n/a
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