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Multiscale and Innovative Kinetic Approaches in Heterogeneous Catalysis

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ISBN: 9783039211791 9783039211807 Year: Pages: 214 DOI: 10.3390/books978-3-03921-180-7 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2019-08-28 11:21:27
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Kinetics and reactor modeling for heterogeneous catalytic reactions are prominent tools for investigating and understanding catalyst functionalities at nanoscale and the related rates of complex reaction networks. This book illustrates some examples related to the transformation of simple to more complex feedstocks, including different types of reactor designs, i.e., steady-state, transient plug flow reactors, and TAP reactors for which there is sometimes a strong gap in the operating conditions from ultra-high-vacuum to high-pressure conditions. In conjunction, new methodologies have emerged, giving rise to more robust microkinetics models. As exemplified, they include the kinetics and the dynamics of the reactors and span a large range of length and time scales. The objective of this Special Issue is to provide contributions that can illustrate recent advances and novel methodologies for elucidating the kinetics of heterogeneous reactions and the necessary multiscale approach for optimizing the reactor design. This book is dedicated to postgraduate and scientific researchers, and experts in heterogeneous catalysis. It may also serve as a source of original information for the elaboration of lessons on catalysis for Master students.

Mineral Surface Reactions at the Nanoscale

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ISBN: 9783038978961 9783038978978 Year: Pages: 220 DOI: 10.3390/books978-3-03897-897-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Geology --- Earth Sciences
Added to DOAB on : 2019-06-26 08:44:06
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Reactions at mineral surfaces are central to all geochemical processes. As minerals comprise the rocks of the Earth, the processes occurring at the mineral–aqueous fluid interface control the evolution of the rocks and hence the structure of the crust of the Earth during processes such as metamorphism, metasomatism, and weathering. In recent years focus has been concentrated on mineral surface reactions made possible through the development of advanced analytical methods such as atomic force microscopy (AFM), advanced electron microscopies (SEM and TEM), phase shift interferometry, confocal Raman spectroscopy, and advanced synchrotron-based applications, to enable mineral surfaces to be imaged and analyzed at the nanoscale. Experiments are increasingly complemented by molecular simulations to confirm or predict the results of these studies. This has enabled new and exciting possibilities to elucidate the mechanisms that govern mineral–fluid reactions. In this Special Issue, “Mineral Surface Reactions at the Nanoscale”, we present 12 contributions that highlight the role and importance of mineral surfaces in varying fields of research.

Bioactive and Therapeutic Dental Materials

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ISBN: 9783039214198 9783039214204 Year: Pages: 216 DOI: 10.3390/books978-3-03921-420-4 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Chemistry (General)
Added to DOAB on : 2019-12-09 11:49:15
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This book focus principally on ions-releasing and other smart dental materials for application in preventive and restorative dentistry, as well as in endodontics in the form of adhesives, resin-based composites, pastes, varnishes, liners and dental cements. Special attention has been given to bioactive materials developed to induce cells differentiation/stimulation, hard tissue formation and exert antimicrobial actions. New innovations are necessary to continue to help reinforcing existing technologies and to introduce new paradigms for treating dental disease and restoring teeth seriously compromised by caries lesions via biomimetic and more biological operative approaches. Dental bioactive materials is arguably the latest research area in dentistry and thus the amount of new research is overwhelming. However, in this day and age of evidence based practice it important for this new information to be distilled into a practical and understandable format.

Keywords

orthodontic resin --- photocatalyst TiO2 --- antibacterial --- cariogenic --- early colonizer --- hydrophilic properties --- irradiation --- calcium silicate cements --- pulpal response --- mineralization --- calcific barrier --- inflammation --- odontoblastic layer --- resin cements --- shrinkage stress --- water sorption --- hydroscopic expansion --- photoelastic investigation --- antibacterial --- calcium --- doxycycline --- nanoparticles --- zinc --- dental composites --- antibacterial properties --- silver --- mechanical properties --- degree of conversion --- sorption --- solubility --- color stability --- mechanical properties --- nanotubes --- resin composite --- Streptococcus mutans --- triclosan --- bleaching products --- diffusion --- cytotoxicity --- dental pulp --- stem cells --- nanoporous silica --- glass-ionomer cement --- calcium --- preclinical biosafety --- bone substitute --- mesenchymal stem cells --- ?-tricalcium phosphate --- tissue engineering --- dental sealant --- resin sealant --- calcium phosphate nanoparticles --- long-term ion release --- remineralization --- ion recharge --- dentin --- desmineralization --- microtensile bond strength --- adhesion --- bioactive --- cycling mechanical stress --- dentine --- longevity --- resin-modified glass ionomer cements --- polyacrylic acid treatment --- bone regeneration --- ?-tricalcium phosphate --- calcium sulfate --- bone substitutes --- animal study --- n/a --- adhesion --- cycling mechanical stress --- dentine --- longevity --- glass-ionomer cements --- universal adhesives

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english (3)


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2019 (3)