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Polymers from Renewable Resources

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ISBN: 9783038974512 9783038974529 Year: Pages: 568 DOI: 10.3390/books978-3-03897-452-9 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General) --- Biochemistry
Added to DOAB on : 2019-01-10 09:45:29
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The use of polymeric materials from renewable resources dates back in history. Even though synthetic polymers dominated the market for years, there is now a need for the development of sustainable, safe, and environmentally benign plastics from renewable resources. Green polymers from renewable resources can be isolated from biomass, obtained through the chemical modification of natural polymers, or synthesized through a two-step process from biomass involving monomer synthesis and then polymerization. Finally, polymer synthesis can be achieved in plants through photosynthesis using carbon dioxide or in microorganisms (e.g. synthesis of poly(hydroxy-alkanoate)s). In this issue, the developments in sustainable polymers including PLA, PHB, and furan-based materials are presented together with those concerning bionanocomposites of lignocellulosic mater or starch, and blends of bioplastics. The use of biomass-based plasticizers, fillers, and additives for the improvement of polymers’ properties and the applications of biopolymers such as hyaluronic acid, carrageenans, chitosan, and polysaccharides in medicine and pharmaceutics are discussed.

Graphene Nanoplatelets

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ISBN: 9783039287949 / 9783039287956 Year: Pages: 140 DOI: 10.3390/books978-3-03928-795-6 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General)
Added to DOAB on : 2020-06-09 16:38:57
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Graphene nanoplatelets (GNPs) have attracted considerable interest due to their exceptional mechanical, electrical, and thermal properties, among others. This book provides a deep review of some aspects related to the characterization of GNPs and their applications as nanoreinforcements for different types of matrices such as polymeric- or cement-based matrices. In this book, the reader will find how these nanoparticles could be used for several industrial applications such as energy production and storage or effective barrier coatings, providing a wide overview of future progress in this topic

Recent Advances in Biocatalysis and Metabolic Engineering for Biomanufacturing

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ISBN: 9783039215744 9783039215751 Year: Pages: 278 DOI: 10.3390/books978-3-03921-575-1 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Biotechnology
Added to DOAB on : 2019-12-09 11:49:15
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The use of biocatalysts, including enzymes and metabolically engineered cells, has attracted a great deal of attention in the chemical and bio-industry, because biocatalytic reactions can be conducted under environmentally-benign conditions and in more sustainable ways. The catalytic efficiency and chemo-, regio-, and stereo-selectivity of enzymes can be enhanced and modulated using protein engineering. Metabolic engineering seeks to enhance cellular biosynthetic productivity of target metabolites via controlling and redesigning metabolic pathways using multi-omics analysis, genome-scale modeling, metabolic flux control, and reconstruction of novel pathways. The aim of this book is to cover the recent advances in biocatalysis and metabolic engineering for biomanufacturing of biofuels, chemicals, biomaterials, and pharmaceuticals. Reviews and original research articles on the development of new strategies to improve the catalytic efficiency of enzymes, biosynthetic capability of cell factories, and their applications in production of various bioproducts and chemicals are included.

Keywords

artificial self-sufficient P450 --- bioplastics --- dodecanoic acid --- Nylon 12 --- ?-aminododecanoic acid --- immobilization --- fluorescein diacetate --- polyurethane foam --- biofilm --- total enzymatic activity --- biocatalysis --- Combi-CLEAs --- cascade reactions --- immobilization --- Myceliophthora --- glyoxal oxidase --- 5-hydroxymethylfurfural --- aerobic methane bioconversion --- bioreactor --- string film reactor --- mass transfer performance --- cross-linked enzyme aggregate --- amyloglucosidase --- magnetic nanoparticles --- bovine serum albumin --- polyethyleneimine --- starch hydrolysis --- Eversa --- interfacial activation --- lipase immobilization --- enzyme stabilization --- enzyme modulation --- metabolic engineering --- synthetic biology --- 3-hydroxypropionic acid --- microbial production --- fatty acid synthesis --- acetate --- redox enzymes --- FTIR spectroscopy --- small molecules --- Corynebacterium glutamicum --- Pvgb --- tunable expression system --- expression vectors --- synthetic biology --- Vitreoscilla --- vgb --- biocatalysts --- biocatalytic reaction --- Methylosinus sporium strain 5 --- soluble methane monooxygenase --- C–H activation --- O2 activation --- synthetic biology --- metabolic engineering --- microbial cell factory --- synthetic metabolic pathways --- mannose --- magnetic nanoparticles --- immobilization --- whole cell --- specific recognition --- 12-hydroxydodecanoic acid --- dodecanoic acid --- CYP153A --- whole-cell biotransformation --- Candida antarctica Lipase B --- transesterification --- polymer functionalization --- tetraethylene glycol --- poly(ethylene glycol) --- hydrogenase --- bio-hydrogen --- chemicals addition --- review --- (?)-?-bisabolol --- mevalonate (MVA) --- mevalonate kinase 1 --- Methanosarcina mazei --- fed-batch fermentation --- monoterpene --- prokaryotic microbial factory --- metabolic engineering --- MEP pathway --- MEV pathway --- n/a

Bio-Based Polymers for Engineered Green Materials

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ISBN: 9783039289257 / 9783039289264 Year: Pages: 568 DOI: 10.3390/books978-3-03928-926-4 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-06-09 16:38:57
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With daily signals, Nature is communicating us that its unconscious wicked exploitation is no more sustainable. Our socio-economic system focuses on production increasing without considering the consequences. We are intoxicating ourselves on a daily bases just to allow the system to perpetuate itself. The time to switch into more natural solutions is come and the scientific community is ready to offer more natural product with comparable performance then the market products we are used to deal with. This book collects a broad set of scientific examples in which research groups from all over the world, aim to replace fossil fuel-based solutions with biomass derived materials. In here, some of the most innovative developments in the field of bio-materials are reported considering topics which goes from biomass valorization to the synthesis of high preforming bio-based materials.

Keywords

thermoplastic starch --- corn starch --- chitosan --- crosslinked microparticles --- lignin-containing cellulose nanofibrils --- poly(lactic acid) and composite films --- lignin content --- compatibility --- adsorption --- phenanthrene --- pyrene --- benzoyl cellulose --- stearoyl cellulose --- silkworm cocoons --- dense structure --- porosity --- robust fiber network --- mechanical properties --- photodegradation --- liquid natural rubber --- UV light --- TiO2 anatase --- latex state --- wood modification --- alkali lignin --- water resistance --- dimensional stability --- heat treatment --- polymeric composites --- antifouling --- metal binding --- iron chelation --- polydopamine coating --- free-radical polymerization --- galactoglucomannan --- lignin --- lignin-carbohydrate complex --- ultrafiltration --- precipitation --- hydrogel --- recycling --- thermal degradation --- mechanical degradation --- polylactic acid --- Bioflex --- Solanyl --- PHBV --- poly(lactic acid) --- pulp fibers --- biocomposite --- emulsion-solvent evaporation method --- films --- mechanical properties --- PHA --- mixed microbial cultures --- bioplastics --- feast-famine --- cost --- Peptone --- Microbial nutrient --- Anti-bacterial silver nanoparticle --- Escherichia coli --- Staphylococcus aureus --- tannin --- hemicellulose --- waste biomass --- HSQC-NMR --- pyrolysis mechanism --- hydrotropic treatment --- metal chloride --- delignification --- enzymatic saccharification --- lignocellulosic nanofibrils --- microencapsulated phase change material (MPCM) --- polylactic acid (PLA) --- toughening --- endothermic effect --- kenaf fiber --- hybrid composites --- bio-based --- film --- mechanical properties --- polysaccharides --- resource recovery --- solution casting --- orange waste --- nanocelluloses --- cellulose nanofibers --- cellulose nanocrystals --- bacterial cellulose --- cement --- fiber-cement --- Hatscheck process --- bio-inspired interfaces --- mechanical properties --- thermal stability --- sensitivity --- electrospinning --- tissue engineering --- paper-based scaffolds --- osteoblast proliferation --- polycaprolactone --- biopolymers --- nanoclays --- nanobiocomposites --- extrusion-compounding --- polyhydroxyalkanoates --- thermal properties --- mechanical properties --- differential scanning calorimetry --- nuclear magnetic resonance --- X-ray diffraction --- transparent wood --- chemical composition --- H2O2 bleaching treatment --- physicochemical properties --- cellulose --- electrical resistance --- copper coating --- electroless deposition --- humidity sensor --- strain sensor --- lyocell fiber --- asphalt rubber --- bio-asphalt --- mixing sequence --- workability --- storage stability --- tung oil --- unsaturated polyester resins --- thermosetting polymers --- structure–property relationship --- structural plastics --- ONP fibers --- silanization --- composites --- mechanical properties --- Artemisia vulgaris --- microcellulose fiber --- nanocellulose fibers --- natural fibers --- Bio-based foams --- wastewater treatments --- cationic dyes --- anionic surfactants --- pollutant adsorbents --- tannin polymer --- tannin-furanic foam --- biopolymers --- nanoclays --- bio-nanocomposites --- extrusion-compounding --- polyhydroxyalkanoates --- thermal properties --- microstructure --- volatiles --- autoxidation --- thermal gravimetric analysis --- scanning electron microscope --- headspace solid phase microextraction --- alginate sponge --- two-step lyophilization --- methylene blue --- adsorption capacity --- biomass resources --- hybrid nonisocyanate polyurethane --- solvent- and catalyst-free --- dimer acid --- melt condensation --- bacterial cellulose --- surface modification --- TEMPO oxidation --- one-pot synthesis --- immobilized TEMPO --- physical property --- skincare --- cellulose --- graphene oxide --- ionic liquid --- membrane --- transport properties --- heavy metals --- porous structure --- SAXS --- WAXS --- cellulose --- wood --- lignocellulose --- ionic liquid --- imidazolium --- fractionation --- dissolution --- GC-MS --- kaempferol --- knotwood --- larixol --- taxifolin --- vibrational spectroscopy --- n/a

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2020 (2)

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