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Zeolite Catalysis

ISBN: 9783038422648 9783038422655 Year: Pages: XIV, 260 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General)
Added to DOAB on : 2016-10-31 17:01:58
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The term zeolite is based on Greek words for “to boil” and “stone” and it is already known since more than 250 years. At that time, the Swedish mineralogist A.F. Cronstedt (1722-1765) observed the formation of large amount of steam when heating the material Stilbite pointing to his porous character and adsorption capacity. At present, over 200 different zeolite frameworks have been identified. In general, zeolites are crystalline aluminosilicates with defined micropore structure. Within zeolites, a good number of elements can be isomorphously incorporated and much more elements or their oxides can be hosted by zeolites. Besides their big variety in size of pore mouths, channels, crossings etc. leading also to their designation as molecular sieves and uses in membrane applications, zeolites reveal Brønsted and Lewis acidic properties that can be varied in wide limits as well. Thus, they deserve the name “solid acids”. Zeolites have an immense importance in diverse industrial applications as catalysts and adsorbents, for example in refinery industry, chemical industry, detergent sector or for solar thermal collectors and adsorption refrigerationIn this special issue we aim at new developments and recent progress with respect to zeolite-catalyzed chemical reactions, adsorption applications and membrane uses as well as improved syntheses strategies and characterization techniques.

New Insights in Stability, Structure and Properties of Porous Materials

Authors: ---
ISBN: 9783038424512 9783038424505 Year: Pages: VIII, 136 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Environmental Sciences
Added to DOAB on : 2017-07-14 08:13:16
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Porous materials (such as zeolites, clay minerals, and assemblies of oxide nanoparticles) are of great importance for the progress of many technological and environmental fields, such as catalysis, adsorption, separation, and ion exchange, because of their unique pore topologies, tunable structures, and the possibility of introducing active reaction sites.The major goal of this Special Issue was to provide a platform for scientists to discuss new insights in the stability, structure, and properties of porous materials, as well as in innovative aspects of their processing and applications. The emphasis was given as the relationships between the structure and/or chemical composition and the specific physical properties of these materials, as well as their role in mineralogical, technological, green, and sustainable processes. In this Special Issue of Minerals, we provide an up-to-date selection of high-quality original and review papers concerning the physical, chemical, and structural characterization of porous materials, the synthesis of crystalline phases with pores in the appropriate range, structure–property relationships at ambient conditions, but also at high temperatures and/or at high pressures, adsorption, and diffusion of mobile species in porous materials, host–guest interactions and confinement effects, ion exchange, modeling in geological and environmental processes, and new insights in processing and applications. In total, eight topical contributions reflect both the diversity and interdisciplinary of modern mineralogy, bridging together experimentalists and computational approaches.

Selective Catalytic Reduction of NOx

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ISBN: 9783038973645 9783038973652 Year: Pages: 280 DOI: 10.3390/books978-3-03897-365-2 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemical Engineering --- Chemistry (General)
Added to DOAB on : 2018-12-14 10:30:46
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The most efficient process to reduce NOx emissions from lean exhaust gases, selective catalytic reduction (SCR) with ammonia, has undergone tremendous development over the past decades. Originally only applied in stationary power plants and industrial installations, SCR systems are now installed in millions of mobile diesel engines, ranging from off-road machineries, to heavy-duty and light-duty trucks and passenger cars, to locomotives and ships. All of these applications involve specific challenges due to tighter emission limits, new internal combustion engine technologies, or alternative fuels.Three review articles and 14 research articles in this book describe recent results and research trends of various aspects of the SCR process. Reaction engineering aspects, such as the proper dosage of ammonia or urea, respectively, are as important as further developments of the different SCR catalysts, by deepening the understanding of their functionality or by systematic improvements of their properties, such as low-temperature activity, selectivity, or poisoning-resistance. Another covered aspect is cost reduction through the use of cheaper base materials for the production is active and stable SCR catalysts. Finally, research efforts are reported to develop SCR processes with different reducing agents, which would open doors to new applications in the future. The range of topics addressed in this book will stimulate the reader’s interest as well as provide a valuable source of information for researchers in academia and industry.

Catalytic Processes for The Valorisation of Biomass Derived Molecules

Authors: --- ---
ISBN: 9783039219148 9783039219155 Year: Pages: 114 DOI: 10.3390/books978-3-03921-915-5 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-12-09 11:49:16
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In the last decades, inedible lignocellulosic biomasses have attracted significant attention for being abundant resources that are not in competition with agricultural land or food production and, therefore, can be used as starting renewable material for the production of a wide variety of platform chemicals. The three main components of lignocellulosic biomasses are cellulose, hemicellulose and lignin, complex biopolymers that can be converted into a pool of platform molecules including sugars, polyols, alchols, ketons, ethers, acids and aromatics. Various technologies have been explored for their one-pot conversion into chemicals, fuels and materials. However, in order to develop new catalytic processes for the selective production of desired products, a complete understanding of the molecular aspects of the basic chemistry and reactivity of biomass derived molecules is still crucial. This Special Issue reports on recent progress and advances in the catalytic valorization of cellulose, hemicellulose and lignin model molecules promoted by novel heterogeneous systems for the production of energy, fuels and chemicals.

Nanoporous Materials and Their Applications

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ISBN: 9783038979685 9783038979692 Year: Pages: 168 DOI: 10.3390/books978-3-03897-969-2 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2019-06-26 08:44:06
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This book is a special collection of articles dedicated to the preparation and characterization of nanoporous materials, such as zeolitic-type materials, mesoporous silica (SBA-15, MCM-41, and KIT-6), mesoporous metallic oxides, metal–organic framework structures (MOFs), and pillared clays, and their applications in adsorption, catalysis, and separation processes. This book presents a global vision of researchers from international universities, research centers, and industries working with nanoporous materials and shares the latest results on the synthesis and characterization of such materials, which have given rise to the special interest in their applications in basic and industrial processes.

Mixed Matrix Membranes

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ISBN: 9783039219766 9783039219773 Year: Pages: 146 DOI: 10.3390/books978-3-03921-977-3 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Chemical Engineering
Added to DOAB on : 2020-01-07 09:08:26
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Mixed matrix membranes (MMMs) have attracted a large amount of interest in research laboratories worldwide in recent decades, motivated by the gap between a growing interest in developing novel mixed matrix membranes by various research groups and the lack of large-scale implementation. This Special Issue contains six publications dealing with the current opportunities and challenges of mixed matrix membranes development and applications to solve environmental and health challenges of the society of 21st century.

Advances in Heterocatalysis by Nanomaterials

Authors: ---
ISBN: 9783039288359 / 9783039288366 Year: Pages: 166 DOI: 10.3390/books978-3-03928-836-6 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Physics (General)
Added to DOAB on : 2020-06-09 16:38:57
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Heterogeneous catalysis played, plays, and will continue to play, a major key role in industrial processes for large-scale synthesis of commodity chemicals of global importance, and in catalytic systems that possess a critical role in energy generation and environmental protection approaches. As a result of the ongoing progress in materials science, nanotechnology, and characterizations, great advances have been achieved in heterogeneous catalysis by nanomaterials. Efficient approaches and advanced methods for the design of nano-structured composite materials (up to atomic level), subject to specific nano-morphologies with enhanced metal–metal and metal–support interactions favorable for catalysis (that enable fine-tuning of the critical properties of the designed catalysts), provide optimized catalysts with outstanding performances in numerous eco-friendly and cost-effective applications. Accordingly, great progress has been achieved involving, for example, emissions control, waste treatment, photocatalytic, bio-refinery, CO2 utilization, and fuel cells applications, as well as hydrocarbon processing for H2, added-value chemicals, and liquid fuels production. The themed Special Issue has succeeded in collecting 10 high-quality contributions that cover recent research progress in the field for a variety of applications (e.g., environment, energy, added-value chemicals/organics synthesis, and bio-transformation) declaring the prospect and importance of nanomaterials in all the directions of heterogeneous catalysis.

Plasma Catalysis

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ISBN: 9783038977506 Year: Pages: 246 DOI: 10.3390/books978-3-03897-751-3 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemical Engineering --- Technology (General)
Added to DOAB on : 2019-04-05 10:34:31
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Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO2 conversion into value-added chemicals and fuels, N2 fixation for the synthesis of NH3 or NOx, methane conversion into higher hydrocarbons or oxygenates. It is also widely used for air pollution control (e.g., VOC

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