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Structural Design and Properties of Coordination Polymers

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ISBN: 9783038428015 9783038428022 Year: Pages: VIII, 122 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Chemistry (General)
Added to DOAB on : 2018-04-27 13:20:05
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Dear Colleagues,The assembly of organic ligands and metal centres yields coordination polymers, many of which find applications in conductivity, catalysis, magnetism, gas sorption, biological sensing and luminescence. The structure and topology of coordination polymers may be manipulated by changing the reaction conditions, leading to a large variety of structurally and topologically unique products. However, controlling and predicting the final outcome of the self-assembly procedure remains one of the major challenges in the field. The final products are often strongly influenced by factors such as the behaviour of a functional group in a molecule, the influence of the crystallization conditions and the various conformations of the components within the crystal.This Special Issue aims to cover a broad range of subjects in coordination polymer chemistry, which are important to the continued growth of the field, showcase current developments and realise its full potential in applications to address major societal challenges.Therefore, we invite you to contribute a research article to this Special Issue and provide a clear snapshot of your research in this field.

Rare Earth and Actinide Complexes

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ISBN: 9783038423294 9783038423287 Year: Pages: X, 254 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Organic Chemistry
Added to DOAB on : 2017-02-20 08:39:06
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As the fields of organometallic and coordination chemistry of the transition metals has grown more mature, the under-explored chemistry of the rare-earths and actinides has drawn the attention of research groups from across the globe looking for new fundamental discoveries and access to compounds with unique properties. The rare-earths—the group 3 metals and the 4f lanthanide series—have long shown many interesting properties in the solid state which exploit their unique electronic configurations. However, it is the molecular chemistry of these metals that has expanded dramatically in recent years as researchers identify the differences between—and unique features of—their molecular compounds. Recent highlights include the identification of new oxidation states and patterns of reactivity as well as applications in medical imaging and health care which represent new and exciting areas of research. The actinides show a wide range of different properties as a consequence of their radioactivity and radiochemistry, but this has not stopped recent rapid progress into the exploration of their unique chemistry. Uranium, in particular, shows huge potential with its transition metal-like range of oxidation states (+2 to +6), and in specialised laboratories, the heavier actinides are also beginning to show their unique chemistry. This Special Issue aims to bring together these strands of research in an openly-accessible way to allow better communication of these advances to a wider audience. This is necessary as, despite these exciting advances, the rare-earths and actinides are still much neglected topics in both school and undergraduate curriculums. Contributions in the above-mentioned areas will allow new research in the rare-earths and actinides to inform and influence the next generation of scientists and keep the field as vibrant as it is today.

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