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Catalyzed Mizoroki–Heck Reaction or C–H activation

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ISBN: 9783039281381 9783039281398 Year: Pages: 182 DOI: 10.3390/books978-3-03928-139-8 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Biology --- Science (General)
Added to DOAB on : 2020-04-07 23:07:08
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In the last few decades, research on the elaboration by palladium-catalytic processes of C-C bonds or the activation of C–H bonds has increased considerably. Yet there is still room for much improvement in terms of selectivity, or enantioselectivity, via the development of new ligands or the study of the catalytic effect of other metals to carry out the same chemical transformations. In addition, the attention paid to environmentally friendly methods in terms of the quantities of catalysts, ligands, and solvents is currently indispensable. The Mizoroki-Heck reaction is one of these important catalytic methods which generates C-C bonds in organic synthesis and is also possible by C-H activation. This book, titled “Catalyzed Mizoroki-Heck Reaction or C-H activation” focuses on new advances in the formation of C-C bonds or new C-H activation methods. It contains original research papers and short reviews on the synthesis of biologically active compounds using these catalytic processes, the identification of new catalysts, of new conditions allowing selectivity or enantioselectivity, the activity and stability of catalyst under turnover conditions, and all improvements in catalytic processes.

Recent Advances in Biocatalysis and Metabolic Engineering for Biomanufacturing

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ISBN: 9783039215744 9783039215751 Year: Pages: 278 DOI: 10.3390/books978-3-03921-575-1 Language: English
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Biotechnology
Added to DOAB on : 2019-12-09 11:49:15
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The use of biocatalysts, including enzymes and metabolically engineered cells, has attracted a great deal of attention in the chemical and bio-industry, because biocatalytic reactions can be conducted under environmentally-benign conditions and in more sustainable ways. The catalytic efficiency and chemo-, regio-, and stereo-selectivity of enzymes can be enhanced and modulated using protein engineering. Metabolic engineering seeks to enhance cellular biosynthetic productivity of target metabolites via controlling and redesigning metabolic pathways using multi-omics analysis, genome-scale modeling, metabolic flux control, and reconstruction of novel pathways. The aim of this book is to cover the recent advances in biocatalysis and metabolic engineering for biomanufacturing of biofuels, chemicals, biomaterials, and pharmaceuticals. Reviews and original research articles on the development of new strategies to improve the catalytic efficiency of enzymes, biosynthetic capability of cell factories, and their applications in production of various bioproducts and chemicals are included.

Keywords

artificial self-sufficient P450 --- bioplastics --- dodecanoic acid --- Nylon 12 --- ?-aminododecanoic acid --- immobilization --- fluorescein diacetate --- polyurethane foam --- biofilm --- total enzymatic activity --- biocatalysis --- Combi-CLEAs --- cascade reactions --- immobilization --- Myceliophthora --- glyoxal oxidase --- 5-hydroxymethylfurfural --- aerobic methane bioconversion --- bioreactor --- string film reactor --- mass transfer performance --- cross-linked enzyme aggregate --- amyloglucosidase --- magnetic nanoparticles --- bovine serum albumin --- polyethyleneimine --- starch hydrolysis --- Eversa --- interfacial activation --- lipase immobilization --- enzyme stabilization --- enzyme modulation --- metabolic engineering --- synthetic biology --- 3-hydroxypropionic acid --- microbial production --- fatty acid synthesis --- acetate --- redox enzymes --- FTIR spectroscopy --- small molecules --- Corynebacterium glutamicum --- Pvgb --- tunable expression system --- expression vectors --- synthetic biology --- Vitreoscilla --- vgb --- biocatalysts --- biocatalytic reaction --- Methylosinus sporium strain 5 --- soluble methane monooxygenase --- C–H activation --- O2 activation --- synthetic biology --- metabolic engineering --- microbial cell factory --- synthetic metabolic pathways --- mannose --- magnetic nanoparticles --- immobilization --- whole cell --- specific recognition --- 12-hydroxydodecanoic acid --- dodecanoic acid --- CYP153A --- whole-cell biotransformation --- Candida antarctica Lipase B --- transesterification --- polymer functionalization --- tetraethylene glycol --- poly(ethylene glycol) --- hydrogenase --- bio-hydrogen --- chemicals addition --- review --- (?)-?-bisabolol --- mevalonate (MVA) --- mevalonate kinase 1 --- Methanosarcina mazei --- fed-batch fermentation --- monoterpene --- prokaryotic microbial factory --- metabolic engineering --- MEP pathway --- MEV pathway --- n/a

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