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Nanocelluloses: Synthesis, Modification and Applications

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ISBN: 9783039287840 / 9783039287857 Year: Pages: 142 DOI: 10.3390/books978-3-03928-785-7 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Biotechnology
Added to DOAB on : 2020-06-09 16:38:57
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Nanocelluloses: Synthesis, Modification and Applications is a book that provides some recent enhancements of various types of nanocellulose, mainly bacterial nanocellulose, cellulose nanocrystals and nanofibrils, and their nanocomposites. Bioactive bacterial nanocellulose finds applications in biomedical applications, https://doi.org/10.3390/nano9101352. Grafting and cross-linking bacterial nanocellulose modification emerges as a good choice for improving the potential of bacterial nanocellulose in such biomedical applications as topical wound dressings and tissue-engineering scaffolds, https://doi.org/10.3390/nano9121668. On the other hand, bacterial nanocellulose can be used as paper additive for fluorescent paper, https://doi.org/10.3390/nano9091322, and for the reinforcement of paper made from recycled fibers, https://doi.org/10.3390/nano9010058. Nanocellulose membranes are used for up-to-date carbon capture applications, https://doi.org/10.3390/nano9060877. Nanocellulose has been applied as a novel component of membranes designed to address a large spectrum of filtration problems, https://doi.org/10.3390/nano9060867. Poly(vinyl alcohol) (PVA) and cellulose nanocrystals (CNC) in random composite mats prepared using the electrospinning method are widely characterized in a large range of physical chemical aspects, https://doi.org/10.3390/nano9050805. Similarly, physical chemical aspects are emphasized for carboxylated cellulose nanofibrils produced by ammonium persulfate oxidation combined with ultrasonic and mechanical treatment, https://doi.org/10.3390/nano8090640. It is extraordinary how nanocellulose can find application in such different fields. Along the same lines, the contributions in this book come from numerous different countries, confirming the great interest of the scientific community for nanocellulose.

Sustainable Utilization of Metals: Processing, Recovery and Recycling

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ISBN: 9783039288854 / 9783039288861 Year: Pages: 388 DOI: 10.3390/books978-3-03928-886-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- Economics
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The high demand for advanced metallic materials raises the need for an extensive recycling of metals and such a sustainable use of raw materials. ""Sustainable Utilization of Metals - Processing, Recovery and Recycling"" comprises the latest scientific achievements in efficient production of metals and such addresses sustainable resource use as part of the circular economy strategy. This policy drives the present contributions, aiming on the recirculation of EoL-streams such as Waste Electric and Electronic Equipment (WEEE), multi-metal alloys or composite materials back into metal production. This needs a holistic approach, resulting in the maximal avoidance of waste. Considering both aspects, circular economy and material design, recovery and use of minor metals play an essential role, since their importance for technological applications often goes along with a lack of supply on the world market. Additionally, their ignoble character and low concentration in recycling materials cause an insufficient recycling rate of these metals, awarding them the status of “critical metals”. In order to minimize losses and energy consumption, this issue explores concepts for the optimization concerning the interface between mechanical and thermal pre-treatment and metallurgical processes. Such new approaches in material design, structural engineering and substitution are provided in the chapters.

Keywords

laterites --- scandium --- leaching --- precipitation --- solvent extraction --- manganese --- Zinc --- electrolytic lodes and scrapings --- electrolytic manganese --- metallurgy --- hydrometallurgy --- recycling --- sustainable development --- recycling --- spent catalysts --- zinc --- copper --- Bayan Obo --- REE–Nb–Fe ore --- carbothermal reduction --- kinetics --- NMC batteries --- recycling --- leaching --- solvent extraction --- selective precipitation --- hydrometallurgy --- Bayer process --- trace elements --- vanadium --- gallium --- rare earth elements --- lanthanum --- yttrium --- scandium --- karst bauxite --- bauxite residue --- red mud --- indium --- silver --- jarosite --- recycling --- industrial residue --- process development --- selective extraction --- simultaneous recovery --- pyrometallurgy --- lifetime of steel --- steel scrap --- circulation --- industry sector --- dynamic material flow model --- recycling rate --- material flow analysis --- gold --- copper --- WPCBs --- leaching --- physical separation --- Tin recovery --- steelmaking dust --- zinc recycling --- alkaline leaching --- electric arc furnace --- Li-ion battery --- recycling --- pyrolysis --- microwave assisted pyrolysis --- battery pre-treatment --- super-gravity --- rheorefining --- aluminum alloy --- tramp element --- separation --- jarosite residue --- pyrometallurgy --- circular economy --- slag valorization --- metal recovery --- closed-loop circulation --- environmentally friendly process --- enrichment of Ti --- preparation for recovery --- reduction of Co --- precipitation --- thermal treatment --- hydrometallurgy --- recycling --- cold-bonded briquettes --- blast furnace --- desulfurization --- basic oxygen furnace --- dust --- sludge --- fines --- scandium --- anti-solvent crystallization --- solvent extraction --- precipitation --- ammonium scandium hexafluoride --- chemical equilibrium diagram --- aluminium purification --- iron removal --- intermetallic formation --- polythermal section --- cerium --- flotation --- glass polishing waste --- gravity separation --- leaching --- precipitation --- rare-earths --- recycling --- reuse --- solvent extraction --- neodymium --- dimethyl sulfoxide --- electrodeposition --- bauxite residue --- red mud --- ionic liquids --- scandium recovery --- titanium recovery --- NdFeB magnets --- rare earth elements --- recycling --- recycling potential --- neodymium --- dysprosium --- WPCB --- melting behavior --- flash smelting --- cementation --- copper removal --- cavitation --- pyrolysis --- smartphone --- displays --- halogenation --- indium --- volatilization --- thermodynamics --- recycling --- magnesium --- refining --- recycling --- ultra-high purity --- vacuum distillation --- condensation --- oxygen-depolarized cathodes --- silver leaching --- cryogenic pre-treatment --- negative activation energy --- polishing waste --- rare earths --- waste utilization --- characterization --- leaching --- n/a

Advances in Hydrometallurgy

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ISBN: 9783039289394 / 9783039289400 Year: Pages: 188 DOI: 10.3390/books978-3-03928-940-0 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General) --- General and Civil Engineering
Added to DOAB on : 2020-06-09 16:38:57
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The development of new technologies and the increasing demand for mineral resources from emerging countries are responsible for significant tensions in the pricing of non-ferrous metals. Some metals have become strategic and critical because they are used in many technological applications such as flat panel TVs (indium), solar panel cells (indium), lithium-ion batteries for electric vehicles (lithium, cobalt), magnets (rare earth elements, such as neodymium and dysprosium), scintillators (rare earths), and aviation and medical applications (titanium); their availabilities remain limited. The secured supply of these metals is crucial to continue producing and exporting these technologies, and because the specific properties of these metals make them essential and difficult to substitute for a given industrial application. Hydrometallurgy have the advantages of being able to process low-grade ores, to allow better control of co-products, and have a lower environmental impact providing that the hydrometallurgical route is optimized and cheap. The need to develop sustainable, efficient, and cheap processes to extract metals from complex and poor polymetallic matrices is real. The aim of this book was to highlight recent advances related to hydrometallurgy to face new challenges in metal production.

Advances in Nanoparticles: Synthesis, Characterization, Theoretical Modelling, and Applications

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ISBN: 9783039285822 / 9783039285839 Year: Pages: 144 DOI: 10.3390/books978-3-03928-583-9 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Technology (General)
Added to DOAB on : 2020-06-09 16:38:56
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This book focuses on recent advances in the synthesis of nanoparticles, their characterization, and their applications in different fields such as catalysis, photonics, magnetism, and nanomedicine. Nanoparticles receive a large share of the worldwide research activity in contemporary materials science. This is witnessed by the number of scientific papers with ""nanoparticle"" as a keyword, increasing linearly in the last 10 years from about 16,000 in 2009 to about 50,000 in 2019. This impressive widespread interest stems from the basic science of nanoparticles, which constitute a bridge between the molecular and the bulk worlds, as well as from their technological applications. The preparation of nanoparticles is a crossroad of materials science where chemists, physicists, engineers, and even biologists frequently meet, leading to a continuous improvement of existing techniques and to the invention of new methods. The reader interested in nanoparticles synthesis and properties will here find a valuable selection of scientific cases that cannot cover all methods and applications relevant to the field, but still provide an updated overview on the fervent research activity focused on nanoparticles.

Cocoa, Chocolate and Human Health

Authors: ---
ISBN: 9783039285884 / 9783039285891 Year: Pages: 288 DOI: 10.3390/books978-3-03928-589-1 Language: eng
Publisher: MDPI - Multidisciplinary Digital Publishing Institute
Subject: Science (General) --- Biology --- Nutrition and Food Sciences
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This book entitled “Cocoa, Chocolate, and Human Health” presents the most recent findings about cocoa and health in 14 peer-reviewed chapters including nine original contributions and five reviews from cocoa experts around the world. Bioavailability and metabolism of the main cocoa polyphenols, i.e., the flavanols like epicatechin, are presented including metabolites like valerolactones that are formed by the gut microbiome. Many studies, including intervention studies or epidemiological observations, do not focus on single compounds, but on cocoa as a whole. This proves the effectiveness of cocoa as a functional food. A positive influence of cocoa on hearing problems, exercise performance, and metabolic syndrome is discussed with mixed results; the results about exercise performance are contradictive. Evidence shows that cocoa flavanols may modulate some risk factors related to metabolic syndrome such as hypertension and disorders in glucose and lipid metabolism. However, several cardiometabolic parameters in type 2 diabetics were not affected by a flavanol-rich cocoa powder as simultaneous treatment with pharmaceuticals might have negated the effect of cocoa. The putative health-promoting components of cocoa are altered during processing like fermentation, drying, and roasting of cocoa beans. Chocolate, the most popular cocoa product, shows remarkable losses in polyphenols and vitamin E during 18 months of storage.

Keywords

type 2 diabetes --- flavanol-rich cocoa --- blood pressure --- glucose metabolism --- lipid status --- type 2 diabetes --- flavanol-rich cocoa --- postprandial --- meal --- glucose metabolism --- lipids --- blood pressure --- cocoa processing --- cocoa proteins --- classification --- extraction and characterization methods --- fermentation-related enzymes --- bioactive peptides --- heath potentials --- protein–phenol interactions --- chocolate --- hearing loss --- tinnitus --- cohort study --- cocoa --- bioactive compounds --- flavanols bioavailability --- anti-inflammatory properties --- metabolic syndrome --- oxidative stress --- cocoa by-product --- functional food --- polyphenols --- ?-glucosidase inhibition --- antidiabetic capacity --- antioxidant capacity --- methylxanthines --- fermentation --- functional volatile compounds --- starter culture --- yeast --- roasting --- chocolate --- cocoa beans --- theobromine --- cacao --- working memory --- behavior --- CaMKII --- CREB --- BDNF --- cocoa --- oligopeptides --- simulated gastrointestinal digestion --- angiotensin-converting enzyme (ACE) inhibitory activity --- cocoa --- chocolate --- metabolites --- biomarkers --- metabolomics --- urine --- plasma --- procyanidins --- methylxanthines --- polyphenols --- flavanols --- soluble cocoa products --- bioavailability --- human --- plasma nutrikinetics --- liquid chromatography coupled to electrospray ionisation and quadrupole time-of-flight mass spectrometry (LC-ESI-QToF-MS) --- colonic bacteria --- athlete --- cocoa --- chocolate --- exercise performance --- oxidative stress --- performance --- physical exercise --- polyphenol --- skeletal muscle --- inflammation --- Italian chocolate --- quality --- cocoa-based ingredients --- monitoring --- nutrition --- cocoa --- flavan-3-ol stereoisomers --- (?)-epicatechin --- (+)-catechin --- (?)-catechin --- plasma appearance --- chiral separation --- pharmacokinetics --- one-compartment model --- n/a

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